PMID- 37147057
OWN - NLM
STAT- MEDLINE
DCOM- 20230508
LR  - 20230508
IS  - 1873-4324 (Electronic)
IS  - 0003-2670 (Linking)
VI  - 1261
DP  - 2023 Jun 22
TI  - Coconut shell biochar application in liquid-solid microextraction of triazine 
      herbicides from multi-media environmental samples.
PG  - 341225
LID - S0003-2670(23)00446-4 [pii]
LID - 10.1016/j.aca.2023.341225 [doi]
AB  - A rapid, fast, widely applicable liquid-solid microextraction and purification 
      method of triazine herbicides (TRZHs) in muti-media samples using salting-out 
      assisted liquid-liquid extraction (SALLE) combined with self-assembled monolithic 
      spin columns-solid phase micro extraction (MSC-SPME) was developed. 
      Environmentally friendly coconut shell biochar (CSB) was used as the adsorbents 
      of MSC-SPME. Ultra-high performance liquid chromatography-tandem mass 
      spectrometry (UPLC-MS/MS) was the separation and determination method. The 
      adsorption kinetics and isotherms were investigated to indicate the interaction 
      between CSB and TRZHs. Several parameters influencing the liquid-solid 
      microextraction efficiency, such as sample pH, salting-out solution volume and 
      pH, sample loading speed, elution speed, elution ratio and volume of eluent were 
      systematically investigated with the aid of orthogonal design. The whole 
      extraction process was operated within 10 min. Under the optimum extraction and 
      determination conditions, good linearities for three TRZHs were obtained in a 
      range of 0.10-200.00 ng mL(-1), with linear coefficients (R(2)) greater than 
      0.999. The limits of detection (LODs) and limits of quantification (LOQs) were in 
      the range of 6.99-11.00 ng L(-1) and 23.33-36.68 ng L(-1), respectively. The 
      recoveries of the three TRZHs in multi-media environmental samples were ranged 
      from 69.00% to 124.72%, with relative standard deviations (RSDs) lower than 
      0.43%. This SALLE-MSC-SPME-UPLC-MS/MS method was successfully applied to the 
      determination of TRZHs in environmental and food samples and exhibited the 
      advantages of high efficiency and sensitivity, low cost, and environmental 
      friendliness. Compared with the methods published before, CSB-MSC was green, 
      rapid, easy-operated, and reduced the whole cost of the experiment; SALLE 
      combined MSC-SPME eliminated the matrix references effectively; what's more, the 
      SALLE-MSC-SPME-UPLC-MS/MS method could be applied to various sample without 
      complicated sample pretreatment procedure.
CI  - Copyright (c) 2023 Elsevier B.V. All rights reserved.
FAU - Ma, Mengge
AU  - Ma M
AD  - Department of Environmental Science, School of Tropical Medicine, International 
      School of Public Health and One Health, Hainan Medical University, Haikou, 
      571199, China.
FAU - Niu, Zongliang
AU  - Niu Z
AD  - Laboratory of Pathogenic Biology and Immunology, School of Basic Medicine and 
      Life Science, Hainan Medical University, Haikou, 571199, China.
FAU - Tang, Zhuhua
AU  - Tang Z
AD  - Key Laboratory of Tropical Fruits and Vegetables Quality and Safety for State 
      Market Regulation, Haikou, China.
FAU - Bai, Jinyang
AU  - Bai J
AD  - Department of Environmental Science, School of Tropical Medicine, International 
      School of Public Health and One Health, Hainan Medical University, Haikou, 
      571199, China.
FAU - Li, Bei
AU  - Li B
AD  - Key Laboratory of Tropical Fruits and Vegetables Quality and Safety for State 
      Market Regulation, Haikou, China.
FAU - Zhou, Yuling
AU  - Zhou Y
AD  - Key Laboratory of Tropical Fruits and Vegetables Quality and Safety for State 
      Market Regulation, Haikou, China. Electronic address: zyl18689983973@163.com.
FAU - Wen, Yingying
AU  - Wen Y
AD  - Department of Environmental Science, School of Tropical Medicine, International 
      School of Public Health and One Health, Hainan Medical University, Haikou, 
      571199, China; Key Laboratory of Tropical Translational Medicine of Ministry of 
      Education, NHC Key Laboratory of Tropical Disease Control, Haikou, 571199, China. 
      Electronic address: wyy_418@163.com.
LA  - eng
PT  - Journal Article
DEP - 20230417
PL  - Netherlands
TA  - Anal Chim Acta
JT  - Analytica chimica acta
JID - 0370534
RN  - 0 (biochar)
RN  - 0 (Herbicides)
RN  - 0 (Triazines)
SB  - IM
MH  - Chromatography, Liquid/methods
MH  - *Cocos
MH  - Tandem Mass Spectrometry/methods
MH  - *Herbicides/analysis
MH  - Chromatography, High Pressure Liquid/methods
MH  - Solid Phase Extraction
MH  - Triazines/analysis
OTO - NOTNLM
OT  - Coconut shell biochar
OT  - Monolithic spin columns-solid phase microextraction
OT  - Multi-media environmental samples
OT  - Salting-out assisted liquid-liquid extraction
OT  - Triazine herbicides
COIS- Declaration of competing interest The authors declare that they have no known 
      competing financial interests or personal relationships that could have appeared 
      to influence the work reported in this paper.
EDAT- 2023/05/06 09:42
MHDA- 2023/05/08 06:41
CRDT- 2023/05/05 20:56
PHST- 2023/01/06 00:00 [received]
PHST- 2023/04/06 00:00 [revised]
PHST- 2023/04/15 00:00 [accepted]
PHST- 2023/05/08 06:41 [medline]
PHST- 2023/05/06 09:42 [pubmed]
PHST- 2023/05/05 20:56 [entrez]
AID - S0003-2670(23)00446-4 [pii]
AID - 10.1016/j.aca.2023.341225 [doi]
PST - ppublish
SO  - Anal Chim Acta. 2023 Jun 22;1261:341225. doi: 10.1016/j.aca.2023.341225. Epub 
      2023 Apr 17.