PMID- 37152582
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20231102
IS  - 2046-2069 (Electronic)
IS  - 2046-2069 (Linking)
VI  - 13
IP  - 20
DP  - 2023 May 2
TI  - A controllably fabricated polypyrrole nanorods network by doping a 
      tetra-beta-carboxylate cobalt phthalocyanine tetrasodium salt for enhanced ammonia 
      sensing at room temperature.
PG  - 13725-13734
LID - 10.1039/d3ra00103b [doi]
AB  - The morphology adjustment and functional doping optimization of polypyrrole (PPy) 
      are of great significance in improving its gas sensing performance. Here, the 
      PPy-0.5TcCoPc nanorods with a uniform dispersed 3-D network were prepared using 
      one-step in situ polymerization using the electrostatic interaction between 
      dopant counterion substituents in tetra-beta-carboxylate cobalt phthalocyanine 
      tetrasodium salt (TcCoPcTs) with larger space structure and pyrrole (Py) 
      molecules, in which TcCoPcTs is not only used as a dopant molecule crosslinking 
      PPy chains to obtain a 3-D network, thus improving the conductivity, but also as 
      a sensor accelerator to improve the gas-sensing performance. The resulting 
      PPy-TcCoPc hybrid exhibits superior NH(3)-sensing properties than PPy and 
      tetra-beta-carboxylate cobalt phthalocyanine (TcCoPc) under the same test 
      conditions, especially the PPy-0.5TcCoPc sensor shows ultrafast response/recovery 
      time to 50 ppm NH(3) (8.1 s/370.8 s), low detection limit of 8.1 ppb and 
      excellent gas selectivity at room temperature (20  degrees C). Besides, the PPy-0.5TcCoPc 
      sensor also maintains superior response (49.3% to 50 ppm NH(3)), humidity 
      resistance and conspicuous stability over 45 days. The excellent NH(3)-sensing 
      performance of the PPy-0.5TcCoPc hybrid arises from the excellent gas selectivity 
      of TcCoPc, the remarkable response mechanism between PPy and NH(3), the high 
      electrical conductivity, abundant active sites and good electron transport 
      ability of the unique 3-D network with large specific surface area. The 
      morphology regulation and functional doping optimization strategy of TcCoPcTs 
      doped PPy broaden the research direction of ideal gas sensor materials.
CI  - This journal is (c) The Royal Society of Chemistry.
FAU - Gai, Shijie
AU  - Gai S
AUID- ORCID: 0000-0002-9986-6239
AD  - Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, 
      School of Chemistry and Materials Science, Heilongjiang University Harbin 150080 
      China wangbin@hlju.edu.cn.
FAU - Wang, Xiaolin
AU  - Wang X
AD  - School of Material and Chemical Engineering, Heilongjiang Institute of Technology 
      Harbin 150050 P. R. China.
FAU - Zhang, Runze
AU  - Zhang R
AD  - Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, 
      School of Chemistry and Materials Science, Heilongjiang University Harbin 150080 
      China wangbin@hlju.edu.cn.
FAU - Zeng, Kun
AU  - Zeng K
AD  - Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, 
      School of Chemistry and Materials Science, Heilongjiang University Harbin 150080 
      China wangbin@hlju.edu.cn.
FAU - Miao, Shoulei
AU  - Miao S
AD  - Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, 
      School of Chemistry and Materials Science, Heilongjiang University Harbin 150080 
      China wangbin@hlju.edu.cn.
FAU - Wu, Yiqun
AU  - Wu Y
AD  - Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, 
      School of Chemistry and Materials Science, Heilongjiang University Harbin 150080 
      China wangbin@hlju.edu.cn.
AD  - Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences P.O. 
      Box 800216 Shanghai 201800 China.
FAU - Wang, Bin
AU  - Wang B
AUID- ORCID: 0000-0002-2703-5663
AD  - Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, 
      School of Chemistry and Materials Science, Heilongjiang University Harbin 150080 
      China wangbin@hlju.edu.cn.
LA  - eng
PT  - Journal Article
DEP - 20230504
PL  - England
TA  - RSC Adv
JT  - RSC advances
JID - 101581657
PMC - PMC10158350
COIS- There are no conflicts to declare.
EDAT- 2023/05/08 06:42
MHDA- 2023/05/08 06:43
PMCR- 2023/05/04
CRDT- 2023/05/08 04:04
PHST- 2023/01/06 00:00 [received]
PHST- 2023/04/13 00:00 [accepted]
PHST- 2023/05/08 06:43 [medline]
PHST- 2023/05/08 06:42 [pubmed]
PHST- 2023/05/08 04:04 [entrez]
PHST- 2023/05/04 00:00 [pmc-release]
AID - d3ra00103b [pii]
AID - 10.1039/d3ra00103b [doi]
PST - epublish
SO  - RSC Adv. 2023 May 4;13(20):13725-13734. doi: 10.1039/d3ra00103b. eCollection 2023 
      May 2.