PMID- 37207425
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20230604
LR  - 20230604
IS  - 1095-7103 (Electronic)
IS  - 0021-9797 (Linking)
VI  - 646
DP  - 2023 Sep 15
TI  - Fabricating Materials of Institute Lavoisier-53(Fe)/zeolite imidazolate 
      framework-8 hybrid materials as high-efficiency and reproducible adsorbents for 
      removing organic pollutants.
PG  - 438-451
LID - S0021-9797(23)00810-X [pii]
LID - 10.1016/j.jcis.2023.05.022 [doi]
AB  - Environmental pollution by emerging contaminants has become an urgent problem. 
      Herein, novel binary metal-organic framework hybrids were constructed from 
      Materials of Institute Lavoisier-53(Fe) (MIL-53(Fe)) and zeolite imidazolate 
      framework-8 (ZIF-8) for the first time. A battery of characterizations were 
      employed to determine the MIL/ZIF hybrids' properties and morphology. 
      Furthermore, the MIL/ZIF towards toxic antibiotics (tetracycline, ciprofloxacin 
      and ofloxacin) were studied to explore their adsorption abilities. The present 
      work disclosed that the obtained MIL-53(Fe)/ZIF-8 = 2:3 possessed an eminent 
      specific surface area with an admirable removal efficiency of tetracycline 
      (97.4%), ciprofloxacin (97.1%) and ofloxacin (92.4%), respectively. The 
      tetracycline adsorption process conformed to the pseudo-second-order kinetic 
      model and this process was more compatible with the Langmuir isotherm model with 
      the highest adsorption capacity of 215.0 mg g(-1). Moreover, the process of 
      removing tetracycline was proved to be spontaneous and exothermic by the 
      thermodynamic results. Furthermore, the MIL-53(Fe)/ZIF-8 = 2:3 towards 
      tetracycline exhibited significant regeneration ability. The effects of pH, 
      dosage, interfering ions and oscillation frequency on tetracycline adsorption 
      capacity and removal efficiency were also investigated. The primary factors 
      contributing to the decent adsorption ability between MIL-53(Fe)/ZIF-8 = 2:3 and 
      tetracycline included electrostatic, pi-pi stacking, hydrogen bonding and weak 
      coordination interactions. Additionally, we also investigated the adsorption 
      ability in real wastewater. Thus, the proposed binary metal-organic framework 
      hybrid materials can be deemed a promising adsorbent in wastewater purification.
CI  - Copyright (c) 2023 Elsevier Inc. All rights reserved.
FAU - Yuan, Ning
AU  - Yuan N
AD  - School of Chemical and Environmental Engineering, China University of Mining and 
      Technology, Beijing 100083, China. Electronic address: ning.yuan@cumtb.edu.cn.
FAU - Zhang, Xinling
AU  - Zhang X
AD  - School of Chemical and Environmental Engineering, China University of Mining and 
      Technology, Beijing 100083, China.
FAU - Chen, Tianxiang
AU  - Chen T
AD  - School of Chemical and Environmental Engineering, China University of Mining and 
      Technology, Beijing 100083, China.
FAU - Xu, Hao
AU  - Xu H
AD  - School of Chemical and Environmental Engineering, China University of Mining and 
      Technology, Beijing 100083, China.
FAU - Wang, Qibao
AU  - Wang Q
AD  - School of Chemical and Environmental Engineering, China University of Mining and 
      Technology, Beijing 100083, China.
LA  - eng
PT  - Journal Article
DEP - 20230509
PL  - United States
TA  - J Colloid Interface Sci
JT  - Journal of colloid and interface science
JID - 0043125
SB  - IM
OTO - NOTNLM
OT  - Adsorption
OT  - Antibiotics
OT  - Mechanism
OT  - Metal-organic frameworks
OT  - Water treatment
COIS- Declaration of Competing Interest The authors declare that they have no known 
      competing financial interests or personal relationships that could have appeared 
      to influence the work reported in this paper.
EDAT- 2023/05/20 09:42
MHDA- 2023/05/20 09:43
CRDT- 2023/05/19 18:02
PHST- 2023/02/08 00:00 [received]
PHST- 2023/04/06 00:00 [revised]
PHST- 2023/05/04 00:00 [accepted]
PHST- 2023/05/20 09:43 [medline]
PHST- 2023/05/20 09:42 [pubmed]
PHST- 2023/05/19 18:02 [entrez]
AID - S0021-9797(23)00810-X [pii]
AID - 10.1016/j.jcis.2023.05.022 [doi]
PST - ppublish
SO  - J Colloid Interface Sci. 2023 Sep 15;646:438-451. doi: 
      10.1016/j.jcis.2023.05.022. Epub 2023 May 9.