PMID- 37223132 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20231031 VI - 2022 DP - 2022 Oct-Nov TI - HYDROPHOBICITY IMPROVEMENTS OF POLYMERS USED IN BIOMEDICAL APPLICATIONS. LID - V004T05A003 [pii] LID - 10.1115/IMECE2022-95610 [doi] AB - Improvement in hydrophobicity is important for polymers used in various applications such as biomedical applications, as it can delay their degradation due to long-term exposure to moisture environments. Although a number of surface modification techniques have been developed over the years to improve hydrophobicity, their specific influences on hydrophobicity enhancement as well as long-term mechanical and tribological performances are yet to be fully understood. In this study, surface textures, with variation in type and geometry, are introduced on Ultrahigh Molecular Weight Polyethylene (UHMWPE) and High Density Polyethylene (HDPE) surfaces to study the effect of surface modification on hydrophobicity and long-term mechanical and tribological performances. Based on the theoretical study using Wenzel and Cassie-Baxter models, surface textures of various types and dimension are introduced on UHMWPE and HDPE surfaces. The results show that introduction of surface textures significantly improves the hydrophobicity of polymers. Specific relationship between texture type and geometry, and improvement in hydrophobicity is explored. Based on the comparison between experimental results and theoretical models, transition state modeling seems to be more suitable in describing the change in hydrophobicity with the addition of surface texture. The study provides useful guidelines to improve hydrophobicity of polymers for biomedical applications. FAU - Hossain, Mohammad Motaher AU - Hossain MM AD - Department of Mechanical & Industrial Engineering, Texas A&M University-Kingsville, Kingsville, TX. FAU - Lokasani, Vinay Reddy AU - Lokasani VR AD - Department of Mechanical & Industrial Engineering, Texas A&M University-Kingsville, Kingsville, TX. LA - eng GR - SC3 GM136636/GM/NIGMS NIH HHS/United States PT - Journal Article DEP - 20230208 PL - United States TA - Int Mech Eng Congress Expo JT - International Mechanical Engineering Congress and Exposition : [proceedings]. International Mechanical Engineering Congress and Exposition JID - 101609945 PMC - PMC10205070 MID - NIHMS1897956 OTO - NOTNLM OT - Polymer OT - hydrophobicity OT - surface texture OT - water contact angle EDAT- 2023/05/24 13:08 MHDA- 2023/05/24 13:09 PMCR- 2023/05/23 CRDT- 2023/05/24 11:43 PHST- 2023/05/24 13:09 [medline] PHST- 2023/05/24 13:08 [pubmed] PHST- 2023/05/24 11:43 [entrez] PHST- 2023/05/23 00:00 [pmc-release] AID - V004T05A003 [pii] AID - 10.1115/IMECE2022-95610 [doi] PST - ppublish SO - Int Mech Eng Congress Expo. 2022 Oct-Nov;2022:V004T05A003. doi: 10.1115/IMECE2022-95610. Epub 2023 Feb 8.