PMID- 37273509
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20230606
IS  - 2296-2646 (Print)
IS  - 2296-2646 (Electronic)
IS  - 2296-2646 (Linking)
VI  - 11
DP  - 2023
TI  - Co-assembly of graphene/polyoxometalate films for highly electrocatalytic and 
      sensing hydroperoxide.
PG  - 1199135
LID - 10.3389/fchem.2023.1199135 [doi]
LID - 1199135
AB  - Graphene oxide (GO) films mixed with polyethylenimine (PEI) were prepared by a 
      layer-by-layer assembly (LBL) method, in which the GO component is then converted 
      to reduced GO (rGO) in situ through an electron transfer interaction with a 
      polyoxometalate (POM) that is assembled on the outer surface. With this, devices 
      were manufactured by spreading composite films of (PEI/rGO)(n)-POM with different 
      numbers of PEI/rGO layers on ITO substrates. Cyclic voltammetry (CV) reveals that 
      the catalytic activity for H(2)O(2) of (PEI/rGO)(n)-POM films was significantly 
      higher than that of similar films of (PEI/GO)(n)/PEI/POM manufactured LBL with 
      the same number of layers, although the catalyst POM content of (PEI/rGO)(n)-POM 
      was only half that of (PEI/GO)(n)/PEI/POM. The catalytic activity of 
      (PEI/rGO)(n)-POM films first increases and then decreases as the number of 
      PEI/rGO layers increases. The result shows that (PEI/rGO)(3)-POM films with three 
      PEI/rGO layers exhibit the highest efficiency. Amperometric measurements of the 
      (PEI/rGO)(3)-POM films showed improved current response, high sensitivity, wide 
      linear range, low detection limit, and fast response for H(2)O(2) detection. The 
      enhanced catalytic property of (PEI/rGO)(n)-POM films is attributed to the 
      electron transfer interaction and electrostatic interaction between POM and rGO.
CI  - Copyright (c) 2023 Bao, Chen, Wang, Liu, Wang, Li and Feng.
FAU - Bao, Yayan
AU  - Bao Y
AD  - School of Chemistry and Material Science, Shanxi Normal University, Linfen, 
      China.
AD  - College of Chemistry and Environmental Engineering, Shanxi Datong University, 
      Datong, China.
FAU - Chen, Zezhong
AU  - Chen Z
AD  - College of Chemistry and Environmental Engineering, Shanxi Datong University, 
      Datong, China.
FAU - Wang, Yuzhen
AU  - Wang Y
AD  - College of Chemistry and Environmental Engineering, Shanxi Datong University, 
      Datong, China.
FAU - Liu, Lizhen
AU  - Liu L
AD  - College of Chemistry and Environmental Engineering, Shanxi Datong University, 
      Datong, China.
FAU - Wang, Haiyan
AU  - Wang H
AD  - College of Chemistry and Environmental Engineering, Shanxi Datong University, 
      Datong, China.
FAU - Li, Zuopeng
AU  - Li Z
AD  - College of Chemistry and Environmental Engineering, Shanxi Datong University, 
      Datong, China.
FAU - Feng, Feng
AU  - Feng F
AD  - School of Chemistry and Material Science, Shanxi Normal University, Linfen, 
      China.
AD  - College of Chemistry and Environmental Engineering, Shanxi Datong University, 
      Datong, China.
LA  - eng
PT  - Journal Article
DEP - 20230518
PL  - Switzerland
TA  - Front Chem
JT  - Frontiers in chemistry
JID - 101627988
PMC - PMC10233151
OTO - NOTNLM
OT  - H2O2
OT  - composite film
OT  - electrocatalytic
OT  - graphene
OT  - polyoxometalate
COIS- The authors declare that the research was conducted in the absence of any 
      commercial or financial relationships that could be construed as a potential 
      conflict of interest.
EDAT- 2023/06/05 13:04
MHDA- 2023/06/05 13:05
PMCR- 2023/01/01
CRDT- 2023/06/05 11:47
PHST- 2023/04/03 00:00 [received]
PHST- 2023/05/03 00:00 [accepted]
PHST- 2023/06/05 13:05 [medline]
PHST- 2023/06/05 13:04 [pubmed]
PHST- 2023/06/05 11:47 [entrez]
PHST- 2023/01/01 00:00 [pmc-release]
AID - 1199135 [pii]
AID - 10.3389/fchem.2023.1199135 [doi]
PST - epublish
SO  - Front Chem. 2023 May 18;11:1199135. doi: 10.3389/fchem.2023.1199135. eCollection 
      2023.