PMID- 37323407
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20230619
IS  - 2470-1343 (Electronic)
IS  - 2470-1343 (Linking)
VI  - 8
IP  - 23
DP  - 2023 Jun 13
TI  - Trace-Level Determination of Triazole Fungicides Using Effervescence-Assisted 
      Liquid-Liquid Microextraction Based on Ternary Deep Eutectic Solvent Prior to 
      High-Performance Liquid Chromatography.
PG  - 21332-21340
LID - 10.1021/acsomega.3c02919 [doi]
AB  - A simple and sensitive preconcentration method, namely, effervescence-assisted 
      liquid-liquid microextraction based on the ternary deep eutectic solvent method, 
      was developed for enrichment of triazole fungicide residues prior to their 
      determination by high-performance liquid chromatography coupled with UV 
      detection. In this method, a ternary deep eutectic solvent (as extractant) was 
      prepared by combination of octanoic acid, decanoic acid, and dodecanoic acid. The 
      solution was well dispersed with sodium bicarbonate (as effervescence powder) 
      without using auxiliary devices. In order to obtain relatively high extraction 
      efficiency, analytical parameters were investigated and optimized. Under optimum 
      conditions, the proposed method showed good linearity within the range of 1-1000 
      mug L(-1) with a coefficient for determination (R(2)) greater than 0.997. The low 
      limits of detection (LODs) were in the range of 0.3-1.0 mug L(-1). The precisions 
      were assessed from the relative standard deviations (RSDs) of retention time and 
      peak area obtained from intra- (n = 3) and inter-day (n = 5 x 5) experiments, 
      which were greater than 1.21 and 4.79%, respectively. Moreover, the proposed 
      method provided high enrichment factors ranging from 112 to 142 folds. A 
      matrix-match calibration method was used for analysis of real samples. Finally, 
      the developed method was successfully applied for determination of the triazole 
      fungicide in environmental water (near agricultural area), honey, and bean 
      samples, and it represents a promising alternative method for analysis of 
      triazoles. The recoveries of the studied triazoles were obtained in the range of 
      82-106% with an RSD less than 4.89.
CI  - (c) 2023 The Authors. Published by American Chemical Society.
FAU - Kachangoon, Rawikan
AU  - Kachangoon R
AD  - Creative Chemistry and Innovation Research Unit, Department of Chemistry and 
      Center of Excellence for Innovation in Chemistry, Faculty of Science, 
      Mahasarakham University, Maha Sarakham 44150, Thailand.
FAU - Vichapong, Jitlada
AU  - Vichapong J
AUID- ORCID: 0000-0003-4637-4465
AD  - Creative Chemistry and Innovation Research Unit, Department of Chemistry and 
      Center of Excellence for Innovation in Chemistry, Faculty of Science, 
      Mahasarakham University, Maha Sarakham 44150, Thailand.
AD  - Multidisciplinary Research Unit of Pure and Applied Chemistry (MRUPAC), 
      Department of Chemistry and Center of Excellent for Innovation in Chemistry, 
      Faculty of Science, Mahasarakham University, Maha Sarakham 44150, Thailand.
FAU - Santaladchaiyakit, Yanawath
AU  - Santaladchaiyakit Y
AD  - Department of Chemistry, Faculty of Engineering, Rajamangala University of 
      Technology Isan, Khon Kaen Campus, Khon Kaen 40000, Thailand.
FAU - Teshima, Norio
AU  - Teshima N
AD  - Department of Applied Chemistry, Aichi Institute of Technology, 1247 Yachigusa, 
      Yakusa-cho, Toyota 470-0392, Japan.
LA  - eng
PT  - Journal Article
DEP - 20230601
PL  - United States
TA  - ACS Omega
JT  - ACS omega
JID - 101691658
PMC - PMC10268287
COIS- The authors declare no competing financial interest.
EDAT- 2023/06/16 06:42
MHDA- 2023/06/16 06:43
PMCR- 2023/06/01
CRDT- 2023/06/16 03:57
PHST- 2023/04/28 00:00 [received]
PHST- 2023/05/23 00:00 [accepted]
PHST- 2023/06/16 06:43 [medline]
PHST- 2023/06/16 06:42 [pubmed]
PHST- 2023/06/16 03:57 [entrez]
PHST- 2023/06/01 00:00 [pmc-release]
AID - 10.1021/acsomega.3c02919 [doi]
PST - epublish
SO  - ACS Omega. 2023 Jun 1;8(23):21332-21340. doi: 10.1021/acsomega.3c02919. 
      eCollection 2023 Jun 13.