PMID- 37375316
OWN - NLM
STAT- MEDLINE
DCOM- 20230629
LR  - 20230701
IS  - 1420-3049 (Electronic)
IS  - 1420-3049 (Linking)
VI  - 28
IP  - 12
DP  - 2023 Jun 14
TI  - The Residue and Dietary Risk Assessment of Spirotetramat and Its Four Metabolites 
      in Cabbage Using Ultra-High-Performance Liquid Chromatography-Tandem Mass 
      Spectrometry.
LID - 10.3390/molecules28124763 [doi]
LID - 4763
AB  - Spirotetramat is a potential tetronic acid pesticide for controlling various 
      pests with piercing-sucking mouthparts. To clarify its dietary risk on cabbage, 
      we established an ultra-high-performance liquid chromatography-tandem mass 
      spectrometry (UHPLC-MS/MS) method and then investigated the residual levels of 
      spirotetramat and its four metabolites in cabbage collected from field 
      experiments under good agricultural practices (GAPs). The average recoveries of 
      spirotetramat and its metabolites in cabbage were 74~110%, while the relative 
      standard deviation (RSD) was 1~6%, and the limit of quantitation (LOQ) was 0.01 
      mg kg(-1). The terminal residue of spirotetramat was in the range of <0.05~0.33 
      mg kg(-1), the chronic dietary risk (RQ(c)) was 17.56%, and the acute dietary 
      risk (RQ(a)) was 0.025~0.049%, which means an acceptable dietary intake risk. 
      This study provides data to guide on the use of spirotetramat and to establish 
      the maximum residue limits (MRLs) of spirotetramat on cabbage.
FAU - Cao, Junli
AU  - Cao J
AUID- ORCID: 0009-0002-8703-0570
AD  - Shanxi Center for Testing of Functional Agro-Products, Longcheng Campus, Shanxi 
      Agricultural University, No. 79, Longcheng Street, Taiyuan 030031, China.
FAU - Li, Jindong
AU  - Li J
AD  - Shanxi Center for Testing of Functional Agro-Products, Longcheng Campus, Shanxi 
      Agricultural University, No. 79, Longcheng Street, Taiyuan 030031, China.
FAU - Ren, Pengcheng
AU  - Ren P
AD  - Shanxi Center for Testing of Functional Agro-Products, Longcheng Campus, Shanxi 
      Agricultural University, No. 79, Longcheng Street, Taiyuan 030031, China.
FAU - Qi, Yanli
AU  - Qi Y
AD  - Shanxi Center for Testing of Functional Agro-Products, Longcheng Campus, Shanxi 
      Agricultural University, No. 79, Longcheng Street, Taiyuan 030031, China.
FAU - Qin, Shu
AU  - Qin S
AD  - Shanxi Center for Testing of Functional Agro-Products, Longcheng Campus, Shanxi 
      Agricultural University, No. 79, Longcheng Street, Taiyuan 030031, China.
LA  - eng
GR  - 2021BQ127/Startup Foundation for Doctors of Shanxi Agricultural University/
GR  - 202103021223149/Shanxi Applied Basic Research Program Science -Youth Technology 
      Research Fund/
GR  - SXBYKY2022087/Award scientific research projects for doctoral graduates who come 
      to work in Shanxi province/
PT  - Journal Article
DEP - 20230614
PL  - Switzerland
TA  - Molecules
JT  - Molecules (Basel, Switzerland)
JID - 100964009
RN  - 4G7KR034OX (spirotetramat)
RN  - 0 (Pesticide Residues)
SB  - IM
MH  - Chromatography, High Pressure Liquid
MH  - *Brassica/chemistry
MH  - Tandem Mass Spectrometry
MH  - Risk Assessment
MH  - *Pesticide Residues/analysis
PMC - PMC10302016
OTO - NOTNLM
OT  - cabbage
OT  - dietary intake risk
OT  - dissipation
OT  - spirotetramat
COIS- The authors declare no conflict of interest.
EDAT- 2023/06/28 06:42
MHDA- 2023/06/29 06:42
PMCR- 2023/06/14
CRDT- 2023/06/28 01:31
PHST- 2023/05/08 00:00 [received]
PHST- 2023/06/03 00:00 [revised]
PHST- 2023/06/09 00:00 [accepted]
PHST- 2023/06/29 06:42 [medline]
PHST- 2023/06/28 06:42 [pubmed]
PHST- 2023/06/28 01:31 [entrez]
PHST- 2023/06/14 00:00 [pmc-release]
AID - molecules28124763 [pii]
AID - molecules-28-04763 [pii]
AID - 10.3390/molecules28124763 [doi]
PST - epublish
SO  - Molecules. 2023 Jun 14;28(12):4763. doi: 10.3390/molecules28124763.