PMID- 37433752
OWN - NLM
STAT- MEDLINE
DCOM- 20231114
LR  - 20231114
IS  - 1097-0010 (Electronic)
IS  - 0022-5142 (Linking)
VI  - 103
IP  - 15
DP  - 2023 Dec
TI  - Simultaneous qualitative and quantitative analyses of volatile components in 
      Chinese honey of six botanical origins using headspace solid-phase 
      microextraction and gas chromatography-mass spectrometry.
PG  - 7631-7642
LID - 10.1002/jsfa.12850 [doi]
AB  - BACKGROUND: Honey aroma is one of its most important properties and it depends on 
      the qualitative and quantitative composition of the volatile compounds. The 
      volatile profile of honey could reveal its botanical origin to avoid a false 
      characterization. Thus, it is of great significance to honey authentication. This 
      study developed and validated a headspace solid-phase microextraction and gas 
      chromatography-mass spectrometry (HS-SPME-GC-MS) method for simultaneous 
      qualitative and quantitative analyses of 34 volatile components in honey. The 
      developed method was applied to 86 honey samples from six different botanical 
      origins, including linden honey, rape honey, jujube honey, vitex honey, lavender 
      honey and acacia honey. RESULTS: The volatile fingerprints and quantitative 
      results were simultaneously obtained by using the full scan and selected ion 
      monitoring (SCAN+SIM) MS scanning mode. The limits of quantification (LOQs) and 
      limits of detection (LODs) of 34 volatile compounds were in the ranges of 
      1-10 ng/g and 0.3-3 ng/g, respectively. And the spiked recoveries ranged between 
      70.6% and 126.2%, with the relative standard deviations (RSDs) not higher than 
      45.4%. A total of 98 volatile compounds were found with relative contents 
      determined, and the 34 volatile compounds were determined with absolute 
      concentrations. Based on the volatile fingerprints and the contents of volatile 
      compounds, honey samples from six botanical origins were well classified by 
      principal component analysis and orthogonal partial least-squares discrimination 
      analysis. CONCLUSIONS: The HS-SPME-GC-MS method was successfully applied to 
      achieve the volatile fingerprints of six types of honey and to quantitatively 
      analyze 34 volatile compounds with satisfying sensitivity and accuracy. 
      Chemometrics analysis showed significant correlations between honey types and 
      volatiles. These results reveal the characteristics of volatile compounds in six 
      types of unifloral honey and provide some supports for honey authentication. (c) 
      2023 Society of Chemical Industry.
CI  - (c) 2023 Society of Chemical Industry.
FAU - Liang, Dongshuang
AU  - Liang D
AD  - Hebei Key Laboratory of Applied Chemistry, College of Environmental and Chemical 
      Engineering, Yanshan University, Qinhuangdao, China.
AD  - Technology Center of Qinhuangdao Customs, Qinhuangdao, China.
FAU - Wen, Haosong
AU  - Wen H
AD  - Technology Center of Qinhuangdao Customs, Qinhuangdao, China.
FAU - Zhou, Yaxuan
AU  - Zhou Y
AD  - Technology Center of Qinhuangdao Customs, Qinhuangdao, China.
FAU - Wang, Taohong
AU  - Wang T
AD  - Technology Center of Qinhuangdao Customs, Qinhuangdao, China.
FAU - Jia, Guangqun
AU  - Jia G
AD  - Technology Center of Qinhuangdao Customs, Qinhuangdao, China.
FAU - Cui, Zongyan
AU  - Cui Z
AUID- ORCID: 0000-0003-0786-8323
AD  - Hebei Key Laboratory of Applied Chemistry, College of Environmental and Chemical 
      Engineering, Yanshan University, Qinhuangdao, China.
AD  - Technology Center of Qinhuangdao Customs, Qinhuangdao, China.
FAU - Li, Adan
AU  - Li A
AD  - Hebei Key Laboratory of Applied Chemistry, College of Environmental and Chemical 
      Engineering, Yanshan University, Qinhuangdao, China.
LA  - eng
GR  - 2019HK090/Scientific Research Projects of the General Administration of Customs 
      of China/
GR  - 2022HK023/Scientific Research Projects of the General Administration of Customs 
      of China/
GR  - B2021203005/Natural Science Foundation of Hebei Province/
PT  - Journal Article
DEP - 20230719
PL  - England
TA  - J Sci Food Agric
JT  - Journal of the science of food and agriculture
JID - 0376334
RN  - 0 (Volatile Organic Compounds)
SB  - IM
MH  - Gas Chromatography-Mass Spectrometry/methods
MH  - *Honey/analysis
MH  - Solid Phase Microextraction/methods
MH  - *Volatile Organic Compounds/chemistry
OTO - NOTNLM
OT  - HS-SPME-GC-MS
OT  - honey
OT  - qualitative and quantitative analyses
OT  - volatiles
EDAT- 2023/07/12 01:07
MHDA- 2023/11/14 06:42
CRDT- 2023/07/11 22:43
PHST- 2023/07/05 00:00 [revised]
PHST- 2023/01/04 00:00 [received]
PHST- 2023/07/12 00:00 [accepted]
PHST- 2023/11/14 06:42 [medline]
PHST- 2023/07/12 01:07 [pubmed]
PHST- 2023/07/11 22:43 [entrez]
AID - 10.1002/jsfa.12850 [doi]
PST - ppublish
SO  - J Sci Food Agric. 2023 Dec;103(15):7631-7642. doi: 10.1002/jsfa.12850. Epub 2023 
      Jul 19.