PMID- 37478941 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20230919 IS - 1879-1026 (Electronic) IS - 0048-9697 (Linking) VI - 899 DP - 2023 Nov 15 TI - Combining spectral analysis and geochemical tracers to investigate surface water-groundwater interactions: A case study in an intensive agricultural setting (southern Guatemala). PG - 165578 LID - S0048-9697(23)04201-8 [pii] LID - 10.1016/j.scitotenv.2023.165578 [doi] AB - An increase in the frequency of severe hydrological events has highlighted the importance of sustainable water management in intensive agricultural regions. In a warming climate, improved understanding and stewardship of water resources are needed to guarantee water supply, ensure food security, and build resilience against extreme events. In this study, we evaluate a framework that combines spectral analysis and geochemical tracers as a potential tool for (1) gaining valuable insights into surface water (SW)-groundwater (GW) interactions, and (2) providing guidance for improved water management in an intensive agricultural basin in southern Guatemala. The framework proves to be useful in revealing important water dynamics, exposing key feedback mechanisms for water availability and quality. With the use of power density functions and hydrochemistry (T, pH, EC, and major ions), two specific interaction regimes (influent and effluent) were identified and delimited for the main watercourse. These segments are estimated to interact at high rates with the shallow aquifer in the river channel proximities and would lose influence towards the basin flanks. Furthermore, the delta(2)H and delta(18)O values indicate that regional groundwater flow systems play an essential role in the basin groundwater recharge. Lastly, we established three influence zones that depict the spatial extent of the SW-GW interactions within the basin. With these zones, we provide recommendations that will allow for further investigation and application into better water management strategies regulating groundwater development and land use activities within the agricultural context of the area. CI - Copyright (c) 2023 The Authors. Published by Elsevier B.V. All rights reserved. FAU - Paiz, Ricardo AU - Paiz R AD - CERIS, Instituto Superior Tecnico, Universidade de Lisboa, Av. Rovisco Pais 1, 1049-001 Lisboa, Portugal. Electronic address: rlmp23@gmail.com. FAU - Low-Calle, Juan Francisco AU - Low-Calle JF AD - Instituto Privado de Investigacion sobre Cambio Climatico, Santa Lucia Cotzumalguapa, Escuintla, Guatemala. FAU - Molina-Estrada, Amy Guicela AU - Molina-Estrada AG AD - Instituto Privado de Investigacion sobre Cambio Climatico, Santa Lucia Cotzumalguapa, Escuintla, Guatemala. FAU - Gil-Villalba, Sergio AU - Gil-Villalba S AD - Instituto Privado de Investigacion sobre Cambio Climatico, Santa Lucia Cotzumalguapa, Escuintla, Guatemala. FAU - Condesso de Melo, Maria Teresa AU - Condesso de Melo MT AD - CERIS, Instituto Superior Tecnico, Universidade de Lisboa, Av. Rovisco Pais 1, 1049-001 Lisboa, Portugal. LA - eng PT - Journal Article DEP - 20230720 PL - Netherlands TA - Sci Total Environ JT - The Science of the total environment JID - 0330500 SB - IM OTO - NOTNLM OT - Alluvial fan OT - Environmental isotopes OT - Guatemala OT - Hydrochemistry OT - Spectral analysis OT - Water management COIS- Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. EDAT- 2023/07/22 10:42 MHDA- 2023/07/22 10:43 CRDT- 2023/07/21 19:22 PHST- 2023/04/15 00:00 [received] PHST- 2023/06/28 00:00 [revised] PHST- 2023/07/14 00:00 [accepted] PHST- 2023/07/22 10:43 [medline] PHST- 2023/07/22 10:42 [pubmed] PHST- 2023/07/21 19:22 [entrez] AID - S0048-9697(23)04201-8 [pii] AID - 10.1016/j.scitotenv.2023.165578 [doi] PST - ppublish SO - Sci Total Environ. 2023 Nov 15;899:165578. doi: 10.1016/j.scitotenv.2023.165578. Epub 2023 Jul 20.