PMID- 37480612
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20230829
IS  - 1873-3336 (Electronic)
IS  - 0304-3894 (Linking)
VI  - 459
DP  - 2023 Oct 5
TI  - First determination on two kinds of microplastic-air partition coefficients of 
      seven per- and polyfluoroalkyl substances under environmentally relative 
      conditions: Experiment measurement and model prediction.
PG  - 132042
LID - S0304-3894(23)01325-0 [pii]
LID - 10.1016/j.jhazmat.2023.132042 [doi]
AB  - Microplastics (MPs) in the environment are the sink and vector of organic 
      contaminants, including per- and polyfluoroalkyl substances (PFASs). Although 
      PFASs are low- and non-volatile compounds, they have the potential to partition 
      and diffuse from MP into the gas phase in the environmental functions. Herein, 
      the MP-air partition coefficient (K(PA)) of seven PFASs was measured using a 
      solid-fugacity meter. The PFAS K(PA) values in two MPs (high-density polyethylene 
      (HDPE) and thermoplastic polyurethane (TPU)) were determined under different 
      times, temperatures, and relative humidities (RH), and a model was developed to 
      predict the PFAS K(PA) values based on the measured data. The results showed that 
      the K(PA) of PFASs increased with the prolonged partition time until 90 mins, and 
      higher temperature and RH facilitated the distribution of PFASs in MPs into the 
      air phase, leading to smaller K(PA) values. Moreover, the derived equation for 
      predicting PFAS log K(PA) values was robust with 0.79 of an adjusted square of 
      correlation coefficient (R(2)(adjusted) = 0.79) and 0.35 of root mean squared 
      error (RMSE = 0.35). These findings provided the first knowledge for 
      understanding the partition behavior and fate of PFASs in the MP-air 
      microenvironment.
CI  - Copyright (c) 2023 Elsevier B.V. All rights reserved.
FAU - Deng, Yun
AU  - Deng Y
AD  - Guangdong Key Laboratory of Environmental Pollution and Health, School of 
      Environment, Jinan University, Guangzhou 510632, China; Key Laboratory of 
      Pollution Processes and Environmental Criteria, Ministry of Education, Tianjin 
      Key Laboratory of Environmental Remediation and Pollution Control, College of 
      Environmental Science and Engineering, Nankai University, Tianjin 300350, PR 
      China.
FAU - Peng, Lin
AU  - Peng L
AD  - Guangdong Key Laboratory of Environmental Pollution and Health, School of 
      Environment, Jinan University, Guangzhou 510632, China; State Key Laboratory of 
      Environmental and Biological Analysis, Department of Chemistry, Hong Kong Baptist 
      University, Hong Kong SAR China.
FAU - Li, Zhendong
AU  - Li Z
AD  - South China Institute of Environmental Sciences, MEE, Guangzhou 510655, China.
FAU - Xu, Wang
AU  - Xu W
AD  - Shenzhen Environmental Monitoring Center, Shenzhen 518049, Guangdong, China.
FAU - Ren, Gang
AU  - Ren G
AD  - Guangdong Key Laboratory of Environmental Pollution and Health, School of 
      Environment, Jinan University, Guangzhou 510632, China.
FAU - Wang, Fei
AU  - Wang F
AD  - Guangdong Key Laboratory of Environmental Pollution and Health, School of 
      Environment, Jinan University, Guangzhou 510632, China. Electronic address: 
      feiwang1984@gmail.com.
LA  - eng
PT  - Journal Article
DEP - 20230711
PL  - Netherlands
TA  - J Hazard Mater
JT  - Journal of hazardous materials
JID - 9422688
SB  - IM
OTO - NOTNLM
OT  - Derived model
OT  - High-density polyethylene (HDPE)
OT  - MP-air partition coefficient (K(PA))
OT  - Per- and polyfluoroalkyl substances (PFASs)
OT  - Thermoplastic polyurethane (TPU)
COIS- Declaration of Competing Interest The authors declare that they have no known 
      competing financial interests or personal relationships that could have appeared 
      to influence the work reported in this paper.
EDAT- 2023/07/23 01:11
MHDA- 2023/07/23 01:12
CRDT- 2023/07/22 18:00
PHST- 2023/05/09 00:00 [received]
PHST- 2023/07/04 00:00 [revised]
PHST- 2023/07/09 00:00 [accepted]
PHST- 2023/07/23 01:12 [medline]
PHST- 2023/07/23 01:11 [pubmed]
PHST- 2023/07/22 18:00 [entrez]
AID - S0304-3894(23)01325-0 [pii]
AID - 10.1016/j.jhazmat.2023.132042 [doi]
PST - ppublish
SO  - J Hazard Mater. 2023 Oct 5;459:132042. doi: 10.1016/j.jhazmat.2023.132042. Epub 
      2023 Jul 11.