PMID- 37531460
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20230816
IS  - 1944-8252 (Electronic)
IS  - 1944-8244 (Linking)
VI  - 15
IP  - 32
DP  - 2023 Aug 16
TI  - Outstanding Energy Storage Performance of NBT-Based Ceramics under Moderate 
      Electric Field Achieved via Antiferroelectric Engineering.
PG  - 38633-38643
LID - 10.1021/acsami.3c08791 [doi]
AB  - Ultrahigh energy-storage performance of dielectric ceramic capacitors is 
      generally achieved under high electric fields (HEFs). However, the HEFs strongly 
      limit the miniaturization, integration, and lifetime of the dielectric 
      energy-storage capacitors. Thus, it is necessary to develop new energy-storage 
      materials with excellent energy-storage densities under moderate electric fields 
      (MEFs). Herein, the antiferroelectric material Ag(0.9)Ca(0.05)NbO(3) (ACN) was 
      used to modify the relaxor ferroelectric material 
      0.6Na(0.5)Bi(0.5)TiO(3)-0.4Sr(0.7)Bi(0.2)TiO(3) (NBT-SBT). The introduction of 
      ACN results in high polarization strength, regulated composition of rhombohedral 
      (R3c) and tetragonal (P4bm), nanodomains, and refined grain size. An outstanding 
      recoverable energy density (W(rec) = 4.6 J/cm(3)) and high efficiency (eta = 82%) 
      were realized under an MEF of 260 kV/cm in 4 mol % ACN-modified NBT-SBT ceramic. 
      The first-principles calculation reveals that the interaction between Bi and O is 
      the intrinsic mechanism of the increased polarization. A new parameter DeltaP/E(b) 
      was proposed to be used as the figure of merit to measure the energy-storage 
      performance under MEFs ( approximately 200-300 kV/cm). This work paves a new way to explore 
      energy-storage materials with excellent-performance MEFs.
FAU - Cao, Wenjun
AU  - Cao W
AUID- ORCID: 0000-0002-4369-1548
AD  - Laboratory of Dielectric Functional Materials, School of Materials Science & 
      Engineering, Anhui University, Hefei 230601, China.
FAU - Li, Li
AU  - Li L
AUID- ORCID: 0000-0003-1169-3394
AD  - Laboratory of Dielectric Functional Materials, School of Materials Science & 
      Engineering, Anhui University, Hefei 230601, China.
FAU - Zhao, Hanyu
AU  - Zhao H
AD  - Laboratory of Dielectric Functional Materials, School of Materials Science & 
      Engineering, Anhui University, Hefei 230601, China.
FAU - Wang, Changyuan
AU  - Wang C
AUID- ORCID: 0009-0003-3822-7200
AD  - Laboratory of Dielectric Functional Materials, School of Materials Science & 
      Engineering, Anhui University, Hefei 230601, China.
FAU - Liang, Cen
AU  - Liang C
AD  - Laboratory of Dielectric Functional Materials, School of Materials Science & 
      Engineering, Anhui University, Hefei 230601, China.
FAU - Li, Feng
AU  - Li F
AD  - Information Materials and Intelligent Sensing Laboratory of Anhui Province, Key 
      Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry 
      of Education, Institutes of Physical Science and Information Technology, Anhui 
      University, Hefei 230601, China.
FAU - Huang, Xuechen
AU  - Huang X
AD  - School of Material and Chemical Engineering, Chuzhou University, Chuzhou 239000, 
      China.
FAU - Wang, Chunchang
AU  - Wang C
AUID- ORCID: 0000-0002-2349-1098
AD  - Laboratory of Dielectric Functional Materials, School of Materials Science & 
      Engineering, Anhui University, Hefei 230601, China.
LA  - eng
PT  - Journal Article
DEP - 20230802
PL  - United States
TA  - ACS Appl Mater Interfaces
JT  - ACS applied materials & interfaces
JID - 101504991
SB  - IM
OTO - NOTNLM
OT  - Na0.5Bi0.5TiO3
OT  - antiferroelectric material
OT  - energy storage parameter
OT  - energy storage performance
OT  - moderate electric fields
EDAT- 2023/08/02 19:15
MHDA- 2023/08/02 19:16
CRDT- 2023/08/02 14:23
PHST- 2023/08/02 19:16 [medline]
PHST- 2023/08/02 19:15 [pubmed]
PHST- 2023/08/02 14:23 [entrez]
AID - 10.1021/acsami.3c08791 [doi]
PST - ppublish
SO  - ACS Appl Mater Interfaces. 2023 Aug 16;15(32):38633-38643. doi: 
      10.1021/acsami.3c08791. Epub 2023 Aug 2.