PMID- 37541473 OWN - NLM STAT- MEDLINE DCOM- 20231023 LR - 20231023 IS - 1879-0003 (Electronic) IS - 0141-8130 (Linking) VI - 249 DP - 2023 Sep 30 TI - Reuse of used paper egg carton boxes as a source to produce hybrid AgNPs- carboxyl nanocellulose through bio-synthesis and its application in active food packaging. PG - 126119 LID - S0141-8130(23)03015-5 [pii] LID - 10.1016/j.ijbiomac.2023.126119 [doi] AB - The proper disposal of disposable synthetic plastic food packaging materials presents a significant challenge for both the environment and the solid waste management community. To address this issue, an antibacterial-based high-strength bio-composite serves as the optimal alternative to conventional packaging materials. This study aims to produce a hybrid material of AgNPs-carboxyl cellulose nanocrystals (AgNPs-CCNCs), obtained from used egg carton boxes (UECBs), through bio acid hydrolysis and an in-situ generation process. Furthermore, AgNPs- carboxyl cellulose nanofibers (AgNPs-CCNFs) will be synthesized through a combination of bio acid hydrolysis and ball milling, followed by an additional in-situ generation step. The AgNPs-carboxyl nanocellulose (AgNPs-CCNCs, and AgNPs-CCNFs) exhibited excellent crystallinity index, morphology, thermal, and antibacterial properties. The morphological analysis was performed by electron microscopy, and the results showed the uniform distribution and spherical form of AgNPs appearing over the carboxyl nanocellulose through the in-situ generation process, which was confirmed through XRD analysis. The study further explores the impact of AgNPs-carboxyl nanocellulose on the mechanical, chemical, antibacterial, and thermal properties of the PVA matrix. The results demonstrate that the bio-nanocomposite film offers opportunities for utilization in active packaging applications. CI - Copyright (c) 2023. Published by Elsevier B.V. FAU - Raghav, G R AU - Raghav GR AD - Department of Mechanical Engineering, SCMS School of Engineering & Technology Karukutty, Cochin, Kerala, India. Electronic address: raghavmechklnce@gmail.com. FAU - Nagarajan, K J AU - Nagarajan KJ AD - Department of Mechatronics Engineering, Thiagarajar College of Engineering, Madurai-625015, Tamil Nadu, India. Electronic address: kjnmech@tce.edu. FAU - Palaninatharaja, M AU - Palaninatharaja M AD - Department of Mechatronics Engineering, Thiagarajar College of Engineering, Madurai-625015, Tamil Nadu, India. Electronic address: pnatharaja@tce.edu. FAU - Karthic, M AU - Karthic M AD - Department of Mechanical Engineering, Thiagarajar College of Engineering, Madurai-625015, Tamil Nadu, India. Electronic address: karthicmanokar@gmail.com. FAU - Kumar, R Ashok AU - Kumar RA AD - Department of Mechanical Engineering, SRM Madurai College for Engineering and Technology, Pottapalayam-630612, Tamil Nadu, India. Electronic address: ashok.hail@gmail.com. FAU - Ganesh, M A AU - Ganesh MA AD - Department of Mechatronics Engineering, Thiagarajar College of Engineering, Madurai-625015, Tamil Nadu, India. Electronic address: ganeshma2015@tce.edu. LA - eng PT - Journal Article DEP - 20230803 PL - Netherlands TA - Int J Biol Macromol JT - International journal of biological macromolecules JID - 7909578 RN - 9004-34-6 (Cellulose) RN - 0 (Anti-Bacterial Agents) SB - IM MH - Food Packaging MH - Cellulose/chemistry MH - *Nanoparticles MH - *Nanocomposites/chemistry MH - Anti-Bacterial Agents/pharmacology/chemistry OTO - NOTNLM OT - AgNPs nanocellulose OT - Antibacterial properties OT - Bio-acid hydrolysis OT - In-situ generation process OT - Urban solid waste COIS- Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. EDAT- 2023/08/05 05:41 MHDA- 2023/10/23 12:45 CRDT- 2023/08/04 19:15 PHST- 2023/06/16 00:00 [received] PHST- 2023/07/21 00:00 [revised] PHST- 2023/08/01 00:00 [accepted] PHST- 2023/10/23 12:45 [medline] PHST- 2023/08/05 05:41 [pubmed] PHST- 2023/08/04 19:15 [entrez] AID - S0141-8130(23)03015-5 [pii] AID - 10.1016/j.ijbiomac.2023.126119 [doi] PST - ppublish SO - Int J Biol Macromol. 2023 Sep 30;249:126119. doi: 10.1016/j.ijbiomac.2023.126119. Epub 2023 Aug 3.