PMID- 37552041
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20230821
IS  - 1520-510X (Electronic)
IS  - 0020-1669 (Linking)
VI  - 62
IP  - 33
DP  - 2023 Aug 21
TI  - Two 3D Two-Fold Interpenetrated Dia-Like Polyoxometalate-Based Metal-Organic 
      Frameworks: Synthesis and Sulfide Selective Oxidation Activity.
PG  - 13221-13229
LID - 10.1021/acs.inorgchem.3c01393 [doi]
AB  - Two new three-dimensional (3D) polyoxometalate-based metal-organic frameworks 
      (POMOFs), [M(2)(btap)(4)(H(2)O)(4)(HPMo(10)(VI) Mo(2)(V)O(40))] (M = Co (1) and 
      Cd (2); btap = 3, 5-bis(1', 2', 4'-triazol-1'-yl)pyridine), have been synthesized 
      under mild hydrothermal conditions and characterized in detail. Single-crystal 
      X-ray diffraction (SXRD) analysis indicates that 1 and 2 are isostructural. In 
      complexes 1 and 2, the metal ion is coordinated with the ligand to form two 
      different left and right helical one-dimensional chains, which are alternately 
      connected in a twisted form to build a two-fold interpenetrated three-dimensional 
      structure, and the polyoxometalate is encapsulated into in the pores generated by 
      the interpenetrating structure. It is noteworthy that 1 and 2, as recyclable 
      catalysts, possess favorable heterogeneous catalytic activity and excellent 
      sulfoxide selectivity in sulfide oxidation reactions, with H(2)O(2) as an 
      oxidant. By reason of the high dispersion of polyoxometalate with good intrinsic 
      activity in the skeleton structure, the title complex has high activity. In 
      addition, no obvious decrease of sulfoxide yield is observed after at least five 
      cycles. These results indicate the excellent catalytic activity and 
      sustainability of 1 and 2.
FAU - Bai, Xue
AU  - Bai X
AD  - Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of 
      Education, College of Chemistry, Northeast Normal University, Changchun, Jilin 
      130024, P. R. China.
FAU - Han, Xu
AU  - Han X
AD  - Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of 
      Education, College of Chemistry, Northeast Normal University, Changchun, Jilin 
      130024, P. R. China.
FAU - Wang, Yuxin
AU  - Wang Y
AD  - Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of 
      Education, College of Chemistry, Northeast Normal University, Changchun, Jilin 
      130024, P. R. China.
FAU - Zhang, Ange
AU  - Zhang A
AD  - Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of 
      Education, College of Chemistry, Northeast Normal University, Changchun, Jilin 
      130024, P. R. China.
FAU - Yang, Yanli
AU  - Yang Y
AD  - Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of 
      Education, College of Chemistry, Northeast Normal University, Changchun, Jilin 
      130024, P. R. China.
FAU - Lu, Ying
AU  - Lu Y
AD  - Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of 
      Education, College of Chemistry, Northeast Normal University, Changchun, Jilin 
      130024, P. R. China.
FAU - Liu, Shuxia
AU  - Liu S
AUID- ORCID: 0000-0003-0235-8594
AD  - Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of 
      Education, College of Chemistry, Northeast Normal University, Changchun, Jilin 
      130024, P. R. China.
LA  - eng
PT  - Journal Article
DEP - 20230808
PL  - United States
TA  - Inorg Chem
JT  - Inorganic chemistry
JID - 0366543
SB  - IM
EDAT- 2023/08/08 12:42
MHDA- 2023/08/08 12:43
CRDT- 2023/08/08 09:43
PHST- 2023/08/08 12:43 [medline]
PHST- 2023/08/08 12:42 [pubmed]
PHST- 2023/08/08 09:43 [entrez]
AID - 10.1021/acs.inorgchem.3c01393 [doi]
PST - ppublish
SO  - Inorg Chem. 2023 Aug 21;62(33):13221-13229. doi: 10.1021/acs.inorgchem.3c01393. 
      Epub 2023 Aug 8.