PMID- 37569249 OWN - NLM STAT- Publisher LR - 20230814 IS - 2304-8158 (Print) IS - 2304-8158 (Electronic) IS - 2304-8158 (Linking) VI - 12 IP - 15 DP - 2023 Aug 7 TI - A Colorimetric Sensor Enabled with Heterogeneous Nanozymes with Phosphatase-like Activity for the Residue Analysis of Methyl Parathion. LID - 10.3390/foods12152980 [doi] LID - 2980 AB - In this study, a colorimetric sensor was developed for the detection of organophosphorus pesticides (OPs) using a heterogeneous nanozyme with phosphatase-like activity. Herein, this heterogeneous nanozyme (Au-pCeO(2)) was obtained by the modification of gold nanoparticles on porous cerium oxide nanorods, resulting in synergistic hydrolysis performance for OPs. Taking methyl parathion (MP) as the target pesticide, the catalytic performance and mechanism of Au-pCeO(2) were investigated. Based on the phosphatase-like Au-pCeO(2), a dual-mode colorimetric sensor for MP was put forward by the analysis of the hydrolysis product via a UV-visible spectrophotometer and a smartphone. Under optimum conditions, this dual-mode strategy can be used for the on-site analysis of MP with concentrations of 5 to 200 muM. Additionally, it can be applied for MP detection in pear and lettuce samples with recoveries ranging from 85.27% to 115.87% and relative standard deviations (RSDs) not exceeding 6.20%, which can provide a simple and convenient method for OP detection in agricultural products. FAU - Zhao, Fengnian AU - Zhao F AUID- ORCID: 0000-0003-2304-7293 AD - College of Chemistry and Materials Engineering, Beijing Technology and Business University, Beijing 100048, China. FAU - Li, Mengyue AU - Li M AD - College of Chemistry and Materials Engineering, Beijing Technology and Business University, Beijing 100048, China. FAU - Wang, Li AU - Wang L AD - College of Chemistry and Materials Engineering, Beijing Technology and Business University, Beijing 100048, China. FAU - Wang, Min AU - Wang M AD - College of Chemistry and Materials Engineering, Beijing Technology and Business University, Beijing 100048, China. LA - eng GR - 32202160/National Natural Science Foundation of China/ GR - QNJJ2022-27/Research Foundation for Youth Scholars of Beijing Technology and Business University/ PT - Journal Article DEP - 20230807 PL - Switzerland TA - Foods JT - Foods (Basel, Switzerland) JID - 101670569 PMC - PMC10418809 OTO - NOTNLM OT - cerium oxide OT - gold nanoparticles OT - heterogeneous nanozyme OT - methyl parathion OT - phosphatase-like activity COIS- The authors declare no conflict of interest. EDAT- 2023/08/12 10:47 MHDA- 2023/08/12 10:47 PMCR- 2023/08/07 CRDT- 2023/08/12 01:07 PHST- 2023/06/20 00:00 [received] PHST- 2023/07/28 00:00 [revised] PHST- 2023/07/31 00:00 [accepted] PHST- 2023/08/12 10:47 [medline] PHST- 2023/08/12 10:47 [pubmed] PHST- 2023/08/12 01:07 [entrez] PHST- 2023/08/07 00:00 [pmc-release] AID - foods12152980 [pii] AID - foods-12-02980 [pii] AID - 10.3390/foods12152980 [doi] PST - epublish SO - Foods. 2023 Aug 7;12(15):2980. doi: 10.3390/foods12152980.