PMID- 37586152
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20230917
IS  - 1095-7103 (Electronic)
IS  - 0021-9797 (Linking)
VI  - 651
DP  - 2023 Dec
TI  - Bagasse cellulose-based S-type Bi(2)O(3)/Zn(3)In(2)S(6) photocatalyst for 
      efficient and stable degradation of 2,4-dichlorophenol under visible light.
PG  - 976-986
LID - S0021-9797(23)01498-4 [pii]
LID - 10.1016/j.jcis.2023.08.028 [doi]
AB  - The environmental and human health hazards posed by 2,4-dichlorophenol (2,4-DCP) 
      call for effective degradation technologies. This research investigates the 
      design and application of a Bi(2)O(3)/Zn(3)In(2)S(6) heterojunction 
      photocatalyst, a 'S scheme', which was constructed via a simple hydrothermal 
      method. The photocatalyst was then embedded in a sugarcane bagasse cellulose 
      carrier (SBC/BO/ZIS), demonstrating excellent 2,4-DCP degradation capacity. The 
      results show that S-type Bi(2)O(3)/Zn(3)In(2)S(6) promotes the separation of 
      photogenerated carriers. The SBC/BO/ZIS complex, in comparison with Bi(2)O(3) and 
      Zn(3)In(2)S(6) alone, amplifies specific surface area (91.7880 m(2)/g) and 
      broadens the light absorption range (570 nm) of materials, showing robust 
      photocatalytic performance. The degradation rate of 50 mg/L 2,4-DCP reached an 
      impressive 97% within 120 min. The encapsulation of BO/ZIS in SBC not only 
      increases the efficiency of material recovery and recycling but also allows for 
      continuous degradation of 2,4-DCP in cyclic manners, maintaining a degradation 
      rate between 90% and 97%. XRD characterization shows that the physical properties 
      of the material are not affected. The degradation of 2,4-DCP was dominantly 
      controlled by active species (.OH and .O(2)(-)) identified by electron 
      paramagnetic resonance analysis and free radical trapping experiments. This 
      innovative design significantly enhances sunlight utilization and effectively 
      curbs charge carrier recombination, while also promoting material recovery and 
      utilization. These attributes establish a foundation for a cost-effective and 
      efficient means of treating actual wastewater containing 2,4-DCP.
CI  - Copyright (c) 2023. Published by Elsevier Inc.
FAU - Liang, Yinna
AU  - Liang Y
AD  - Guangxi Key Laboratory of Clean Pulp & Papermaking and Pollution Control, School 
      of Light Industry Technology and Engineering, Guangxi University, Nanning 530004, 
      China.
FAU - Xiong, Jianhua
AU  - Xiong J
AD  - School of Resources, Environment and Materials, Guangxi University, Nanning 
      530004, China. Electronic address: xjh@gxu.edu.cn.
FAU - Yang, Qifeng
AU  - Yang Q
AD  - Guangxi Bossco Environmental Protection Technology Co., Ltd., Nanning 530007, 
      China.
FAU - Wang, Shuangfei
AU  - Wang S
AD  - Guangxi Key Laboratory of Clean Pulp & Papermaking and Pollution Control, School 
      of Light Industry Technology and Engineering, Guangxi University, Nanning 530004, 
      China. Electronic address: wangsf@gxu.edu.cn.
LA  - eng
PT  - Journal Article
DEP - 20230807
PL  - United States
TA  - J Colloid Interface Sci
JT  - Journal of colloid and interface science
JID - 0043125
SB  - IM
OTO - NOTNLM
OT  - Bi(2)O(3)/Zn(3)In(2)S(6) immobilization
OT  - Organic pollutant degradation
OT  - Photocatalytic degradation
OT  - S-type heterojunction
OT  - Sugarcane bagasse cellulose
COIS- Declaration of Competing Interest The authors declare that they have no known 
      competing financial interests or personal relationships that could have appeared 
      to influence the work reported in this paper.
EDAT- 2023/08/17 00:42
MHDA- 2023/08/17 00:43
CRDT- 2023/08/16 18:02
PHST- 2023/06/14 00:00 [received]
PHST- 2023/07/26 00:00 [revised]
PHST- 2023/08/05 00:00 [accepted]
PHST- 2023/08/17 00:43 [medline]
PHST- 2023/08/17 00:42 [pubmed]
PHST- 2023/08/16 18:02 [entrez]
AID - S0021-9797(23)01498-4 [pii]
AID - 10.1016/j.jcis.2023.08.028 [doi]
PST - ppublish
SO  - J Colloid Interface Sci. 2023 Dec;651:976-986. doi: 10.1016/j.jcis.2023.08.028. 
      Epub 2023 Aug 7.