PMID- 37591801 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20230831 IS - 1759-9679 (Electronic) IS - 1759-9660 (Linking) VI - 15 IP - 34 DP - 2023 Aug 31 TI - One-pot preparation of supramolecularly functionalized silver nanoparticles for surface plasmon resonance based dual-modal sensing of phytotoxic polychlorinated biphenyl. PG - 4268-4274 LID - 10.1039/d3ay01137b [doi] AB - Polychlorinated biphenyls (PCBs), as a member of persistent organic pollutants (POPs), have posed a risk to humans and the environment until today. The monitoring of phytotoxic PCB which is toxic to plants, is especially important for ecological early warning and pollution management. In this work, beta-cyclodextrin modified silver nanoparticles are prepared in a one-pot method, integrating the synthesis and surface modification in one step. The nanoparticles can supramolecularly immobilize 2,4,4'-trichlorobiphenyl (PCB 28) on their surface and construct a surface plasmon resonance-based nanosensor. Surface plasmon-resonance light scattering and surface-enhanced Raman scattering sensing of PCB 28 are realized using the nanosensor. The dual-modal sensing shows excellent performance for the potential practical monitoring of phytotoxic POPs in the plant and its growing environment. FAU - Cui, Jingcheng AU - Cui J AD - School of Municipal and Environmental Engineering, Shandong Jianzhu University, Jinan 250101, Shandong, China. sdjzusers@163.com. FAU - Chen, Shichao AU - Chen S AD - Department of Pharmacy, Affiliated Hospital of Shandong University of Traditional Chinese Medicine, Jinan 250014, Shandong, China. FAU - Wang, Yu AU - Wang Y AD - School of Municipal and Environmental Engineering, Shandong Jianzhu University, Jinan 250101, Shandong, China. sdjzusers@163.com. FAU - Ji, Zhongyuan AU - Ji Z AD - Characteristic Laboratory of Forensic Science in Universities of Shandong Province, Shandong University of Political Science and Law, Jinan 250014, Shandong, P. R. China. FAU - Lu, Wenhui AU - Lu W AD - Characteristic Laboratory of Forensic Science in Universities of Shandong Province, Shandong University of Political Science and Law, Jinan 250014, Shandong, P. R. China. FAU - Zhu, Yanyan AU - Zhu Y AD - School of Municipal and Environmental Engineering, Shandong Jianzhu University, Jinan 250101, Shandong, China. sdjzusers@163.com. FAU - Ma, Yongshan AU - Ma Y AUID- ORCID: 0000-0003-0652-5695 AD - School of Municipal and Environmental Engineering, Shandong Jianzhu University, Jinan 250101, Shandong, China. sdjzusers@163.com. FAU - Chen, Feiyong AU - Chen F AD - Research Institute of Resources and Environmental Innovation, Shandong Jianzhu University, Jinan 250101, China. FAU - Zhang, Guiqin AU - Zhang G AUID- ORCID: 0009-0000-9632-7937 AD - School of Municipal and Environmental Engineering, Shandong Jianzhu University, Jinan 250101, Shandong, China. sdjzusers@163.com. LA - eng PT - Journal Article DEP - 20230831 PL - England TA - Anal Methods JT - Analytical methods : advancing methods and applications JID - 101519733 SB - IM EDAT- 2023/08/18 00:42 MHDA- 2023/08/18 00:43 CRDT- 2023/08/17 22:53 PHST- 2023/08/18 00:43 [medline] PHST- 2023/08/18 00:42 [pubmed] PHST- 2023/08/17 22:53 [entrez] AID - 10.1039/d3ay01137b [doi] PST - epublish SO - Anal Methods. 2023 Aug 31;15(34):4268-4274. doi: 10.1039/d3ay01137b.