PMID- 37668001 OWN - NLM STAT- MEDLINE DCOM- 20240429 LR - 20240429 IS - 1369-1619 (Electronic) IS - 0960-3123 (Linking) VI - 34 IP - 6 DP - 2024 Jun TI - Determination of pesticide residues in varieties of pepper sold at different periods and provinces in Turkey and investigation of their adverse effects on human health and the environment. PG - 2491-2503 LID - 10.1080/09603123.2023.2254720 [doi] AB - Pesticides are dangerous chemicals that can harm to people and the environment when applied inappropriately or in excess. In this research, various pesticide residues were investigated in 48 pepper samples using liquid chromatography-tandem mass spectrometry (LC-MS/MS). All samples were collected randomly in two periods of time (September and December) from markets and greengrocers in four provinces (Siirt, Mardin, Diyarbakir, and Batman). Considering the means of the first and second periods, diclofop-methyl had the highest concentration of 29.4 +/- 7.7 microg kg(-1), and diazinon had the lowest of 21.1 +/- 4.6 microg kg(-1). Based on the maximum residue limits (MRLs) of pesticides specified in the Turkish Food Codex, pyrimethanil, bupirimate, and diclofop-methyl were found to be below the maximum acceptable residue limit, while pyridaphention, dinoseb, diazinon, and pirimiphos-methyl were found to be above the limit. Thus, the current study demonstrated the potential of LC-MS/MS as a crucial technique for accurate measurements and confirmations of pesticides in different pepper varieties. FAU - Aktas, Serafettin AU - Aktas S AD - Faculty of Arts and Science, Department of Chemistry, Siirt University, Siirt, Turkey. FAU - Aminzai, Mohammad Tahir AU - Aminzai MT AD - Department of Organic Chemistry, Faculty of Chemistry, Kabul University, Kabul, Afghanistan. FAU - Tegin, Ibrahim AU - Tegin I AD - Faculty of Arts and Science, Department of Chemistry, Siirt University, Siirt, Turkey. FAU - Yabalak, Erdal AU - Yabalak E AUID- ORCID: 0000-0002-4009-4174 AD - Department of Nanotechnology and Advanced Materials, Mersin University, Mersin, Turkey. FAU - Acar, Orhan AU - Acar O AD - Faculty of Science, Department of Chemistry, Gazi University, Ankara, Turkey. LA - eng PT - Journal Article DEP - 20230905 PL - England TA - Int J Environ Health Res JT - International journal of environmental health research JID - 9106628 RN - 0 (Pesticide Residues) SB - IM MH - Turkey MH - *Pesticide Residues/analysis MH - *Tandem Mass Spectrometry MH - *Capsicum/chemistry MH - *Food Contamination/analysis MH - Chromatography, Liquid MH - Humans MH - Environmental Monitoring OTO - NOTNLM OT - LC-MS/MS OT - Pesticides OT - food monitoring, maximum residue limits OT - health hazards OT - pepper EDAT- 2023/09/05 06:42 MHDA- 2024/04/29 13:57 CRDT- 2023/09/05 05:33 PHST- 2024/04/29 13:57 [medline] PHST- 2023/09/05 06:42 [pubmed] PHST- 2023/09/05 05:33 [entrez] AID - 10.1080/09603123.2023.2254720 [doi] PST - ppublish SO - Int J Environ Health Res. 2024 Jun;34(6):2491-2503. doi: 10.1080/09603123.2023.2254720. Epub 2023 Sep 5.