PMID- 37688271 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20230911 IS - 2073-4360 (Electronic) IS - 2073-4360 (Linking) VI - 15 IP - 17 DP - 2023 Sep 4 TI - Optimization of Thermal Conductivity and Tensile Properties of High-Density Polyethylene by Addition of Expanded Graphite and Boron Nitride. LID - 10.3390/polym15173645 [doi] LID - 3645 AB - Due to its mechanical, rheological, and chemical properties, high-density polyethylene (HDPE) is commonly used as a material for producing the pipes for transport of various media. Low thermal conductivity (0.4 W/mK) narrows down the usage of HDPE in the heat exchanger systems. The main goal of the work is to reduce the vertical depth of the HDPE pipe buried in the borehole by increasing the thermal conductivity of the material. This property can be improved by adding certain additives to the pure HDPE matrix. Composites made of HDPE with metallic and non-metallic additives show increased thermal conductivity several times compared to the thermal conductivity of pure HDPE. Those additives affect the mechanical properties too, by enhancing or degrading them. In this research, the thermal conductivity and tensile properties of composite made of HDPE matrix and two types of additives, expanded graphite (EG) and boron nitride (BN), were tested. Micro-sized particles of EG and two different sizes of BN particles, micro and nano, were used to produce composite. The objective behind utilizing composite materials featuring dual additives is twofold: firstly, to enhance thermal properties, and secondly, to improve mechanical properties when compared with the pure HDPE. As anticipated, the thermal conductivity of the composites exhibited an eightfold rise in comparison to the pure HDPE. The tensile modulus experienced augmentation across all variations of additive ratios within the composites, albeit with a marginal reduction in tensile strength. This implies that the composite retains a value similar to pure HDPE in terms of tensile strength. Apart from the enhancement observed in all the aforementioned properties, the most significant downside of these composites pertains to their strain at yield, which experienced a reduction, declining from the initial 8.5% found in pure HDPE to a range spanning from 6.6% to 1.8%, dependent upon the specific additive ratios and the size of the BN particles. FAU - Travas, Lovro AU - Travas L AD - Faculty of Mechanical Engineering and Naval Architecture, University of Zagreb, Ivana Lucica 5, 10000 Zagreb, Croatia. FAU - Rujnic Havstad, Maja AU - Rujnic Havstad M AUID- ORCID: 0000-0002-0700-9388 AD - Faculty of Mechanical Engineering and Naval Architecture, University of Zagreb, Ivana Lucica 5, 10000 Zagreb, Croatia. FAU - Pilipovic, Ana AU - Pilipovic A AUID- ORCID: 0000-0003-1330-6458 AD - Faculty of Mechanical Engineering and Naval Architecture, University of Zagreb, Ivana Lucica 5, 10000 Zagreb, Croatia. LA - eng GR - KK.01.2.1.02/Competitiveness and Cohesion 2014-2020/ PT - Journal Article DEP - 20230904 PL - Switzerland TA - Polymers (Basel) JT - Polymers JID - 101545357 PMC - PMC10489680 OTO - NOTNLM OT - HDPE pipe OT - boron nitride OT - composite OT - expanded graphite OT - tensile properties OT - thermal conductivity COIS- The authors declare no conflict of interest. EDAT- 2023/09/09 11:46 MHDA- 2023/09/09 11:47 PMCR- 2023/09/04 CRDT- 2023/09/09 01:25 PHST- 2023/08/08 00:00 [received] PHST- 2023/08/27 00:00 [revised] PHST- 2023/08/30 00:00 [accepted] PHST- 2023/09/09 11:47 [medline] PHST- 2023/09/09 11:46 [pubmed] PHST- 2023/09/09 01:25 [entrez] PHST- 2023/09/04 00:00 [pmc-release] AID - polym15173645 [pii] AID - polymers-15-03645 [pii] AID - 10.3390/polym15173645 [doi] PST - epublish SO - Polymers (Basel). 2023 Sep 4;15(17):3645. doi: 10.3390/polym15173645.