PMID- 37716344 OWN - NLM STAT- MEDLINE DCOM- 20231103 LR - 20231103 IS - 1873-376X (Electronic) IS - 1570-0232 (Linking) VI - 1229 DP - 2023 Sep 1 TI - Preparation and application of an imidazolium-based poly (ionic liquid) functionalized silica sorbent for solid-phase extraction of parabens from food samples. PG - 123888 LID - S1570-0232(23)00298-2 [pii] LID - 10.1016/j.jchromb.2023.123888 [doi] AB - In this work, an imidazolium-based poly (ionic liquid) (poly(1-octyl-3-vinyl- imidazolium naphthalene sulfonate)) functionalized silica (poly(C(8)VIm(+)NapSO(3)(-)) @SiO(2)) was successfully prepared for the determination of parabens in food samples. The prepared poly(C(8)VIm(+)NapSO(3)(-))@SiO(2) was characterized by Fourier transform infrared spectrometry (FT-IR), X-ray photoelectron spectrogram (XPS) and Scanning electron microscopy (SEM). The simulation calculation results indicated that the suitable binding energies were between the polymeric ionic liquids and parabens, and the main interactions for extraction were hydrogen bonding, electrostatic and pi-pi stacking interactions. In addition, compared with commercial extraction materials, the prepared poly(C(8)VIm(+)NapSO(3)(-))@SiO(2) sorbent showed comparable or even better extraction performance towards parabens. The effective parameters were optimized by a combination of the univariate method and Box-Behnken design (BBD). Under the optimum conditions, coupled with high performance liquid chromatography (HPLC), wide linear ranges (1.0-800 mug L(-1)), good linearity (R(2) >/= 0.9997) and low limits of detection (0.1 mug L(-1)) were obtained. In addition, the intra-day and inter-day relative standard deviations (RSDs) were all lower than 6.3%. Moreover, the proposed method was successfully used for the determination of parabens in food samples and satisfactory recoveries in the range of 76.9-97.4% were obtained. The results indicated that the proposed method had good sensitivity, accuracy and precision for the detection of parabens in food samples. CI - Copyright (c) 2023 Elsevier B.V. All rights reserved. FAU - Liu, Na AU - Liu N AD - State Key Laboratory of Biobased Material and Green Papermaking, School of Food Science and Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, China. FAU - Wang, Na AU - Wang N AD - State Key Laboratory of Biobased Material and Green Papermaking, School of Food Science and Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, China. Electronic address: rizhaowangna1222@163.com. FAU - Yang, Ting AU - Yang T AD - State Key Laboratory of Biobased Material and Green Papermaking, School of Food Science and Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, China. FAU - Zhou, Xuesheng AU - Zhou X AD - Key Laboratory of Transportation Industry for Transport Vehicle Detection, Diagnosis and Maintenance Technology, School of Automotive Engineering, ShanDong JiaoTong University, Jinan 250357, China. FAU - Chai, Qingqing AU - Chai Q AD - State Key Laboratory of Biobased Material and Green Papermaking, School of Food Science and Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, China. FAU - Liu, Guimei AU - Liu G AD - State Key Laboratory of Biobased Material and Green Papermaking, School of Food Science and Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, China. FAU - Cui, Bo AU - Cui B AD - State Key Laboratory of Biobased Material and Green Papermaking, School of Food Science and Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, China. Electronic address: cuibopaper@163.com. LA - eng PT - Journal Article DEP - 20230912 PL - Netherlands TA - J Chromatogr B Analyt Technol Biomed Life Sci JT - Journal of chromatography. B, Analytical technologies in the biomedical and life sciences JID - 101139554 RN - 0 (Ionic Liquids) RN - 7631-86-9 (Silicon Dioxide) RN - 0 (Parabens) RN - 2166IN72UN (naphthalene) SB - IM MH - *Ionic Liquids/chemistry MH - Silicon Dioxide/chemistry MH - Parabens/analysis MH - Spectroscopy, Fourier Transform Infrared MH - Adsorption MH - Solid Phase Extraction/methods MH - Chromatography, High Pressure Liquid/methods MH - Limit of Detection OTO - NOTNLM OT - Binding energies OT - Parabens OT - Polymeric ionic liquids OT - Response surface methodology OT - Solid-phase extraction COIS- Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. EDAT- 2023/09/17 00:41 MHDA- 2023/11/03 06:44 CRDT- 2023/09/16 18:12 PHST- 2023/07/22 00:00 [received] PHST- 2023/09/01 00:00 [revised] PHST- 2023/09/11 00:00 [accepted] PHST- 2023/11/03 06:44 [medline] PHST- 2023/09/17 00:41 [pubmed] PHST- 2023/09/16 18:12 [entrez] AID - S1570-0232(23)00298-2 [pii] AID - 10.1016/j.jchromb.2023.123888 [doi] PST - ppublish SO - J Chromatogr B Analyt Technol Biomed Life Sci. 2023 Sep 1;1229:123888. doi: 10.1016/j.jchromb.2023.123888. Epub 2023 Sep 12.