PMID- 37730213 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20240104 IS - 1521-4095 (Electronic) IS - 0935-9648 (Linking) VI - 36 IP - 1 DP - 2024 Jan TI - Inorganic All-Solid-State Sodium Batteries: Electrolyte Designing and Interface Engineering. PG - e2308332 LID - 10.1002/adma.202308332 [doi] AB - Inorganic all-solid-state sodium batteries (IASSSBs) are emerged as promising candidates to replace commercial lithium-ion batteries in large-scale energy storage systems due to their potential advantages, such as abundant raw materials, robust safety, low price, high-energy density, favorable reliability and stability. Inorganic sodium solid electrolytes (ISSEs) are an indispensable component of IASSSBs, gaining significant attention. Herein, this review begins by discussing the fundamentals of ISSEs, including their ionic conductivity, mechanical property, chemical and electrochemical stabilities. It then presents the crystal structures of advanced ISSEs (e.g., beta/beta''-alumina, NASICON, sulfides, complex hydride and halide electrolytes) and the related issues, along with corresponding modification strategies. The review also outlines effective approaches for forming intimate interfaces between ISSEs and working electrodes. Finally, current challenges and critical perspectives for the potential developments and possible directions to improve interfacial contacts for future practical applications of ISSEs are highlighted. This comprehensive review aims to advance the understanding and development of next-generation rechargeable IASSSBs. CI - (c) 2023 Wiley-VCH GmbH. FAU - Yang, Yaxiong AU - Yang Y AD - Institute of Science and Technology for New Energy, Xi'an Technological University, Xi'an, 710021, China. FAU - Yang, Shoumeng AU - Yang S AD - School of Materials and Energy, Guangdong University of Technology, Guangzhou, 510006, China. FAU - Xue, Xu AU - Xue X AD - Institute of Science and Technology for New Energy, Xi'an Technological University, Xi'an, 710021, China. FAU - Zhang, Xianghua AU - Zhang X AD - School of Materials and Energy, Guangdong University of Technology, Guangzhou, 510006, China. FAU - Li, Qifei AU - Li Q AD - School of Materials and Energy, Guangdong University of Technology, Guangzhou, 510006, China. FAU - Yao, Yu AU - Yao Y AD - Hefei National Research Center for Physical Sciences at the Microscale, Department of Materials Science and Engineering, CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China, Hefei, Anhui, 230026, China. FAU - Rui, Xianhong AU - Rui X AD - School of Materials and Energy, Guangdong University of Technology, Guangzhou, 510006, China. FAU - Pan, Hongge AU - Pan H AD - Institute of Science and Technology for New Energy, Xi'an Technological University, Xi'an, 710021, China. FAU - Yu, Yan AU - Yu Y AUID- ORCID: 0000-0002-3685-7773 AD - Hefei National Research Center for Physical Sciences at the Microscale, Department of Materials Science and Engineering, CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China, Hefei, Anhui, 230026, China. LA - eng GR - 51925207/National Natural Science Foundation of China/ GR - 52372239/National Natural Science Foundation of China/ GR - 52161145101/National Natural Science Foundation of China/ GR - U1910210/National Natural Science Foundation of China/ GR - 52102322/National Natural Science Foundation of China/ GR - WK2060000055/Fundamental Research Funds for the Central Universities/ GR - WK2400000004/Fundamental Research Funds for the Central Universities/ GR - WK2060140026/Fundamental Research Funds for the Central Universities/ GR - KY2060000173/National Synchrotron Radiation Laboratory/ GR - 2021002/Joint Fund of the Yulin University and the Dalian National Laboratory for Clean Energy/ PT - Journal Article PT - Review DEP - 20231120 PL - Germany TA - Adv Mater JT - Advanced materials (Deerfield Beach, Fla.) JID - 9885358 SB - IM OTO - NOTNLM OT - all-solid-state sodium batteries OT - chemical and electrochemical stability OT - inorganic sodium solid electrolytes OT - interface compatibility OT - ionic conductivity EDAT- 2023/09/21 00:42 MHDA- 2023/09/21 00:43 CRDT- 2023/09/20 20:02 PHST- 2023/09/11 00:00 [revised] PHST- 2023/08/16 00:00 [received] PHST- 2023/09/21 00:43 [medline] PHST- 2023/09/21 00:42 [pubmed] PHST- 2023/09/20 20:02 [entrez] AID - 10.1002/adma.202308332 [doi] PST - ppublish SO - Adv Mater. 2024 Jan;36(1):e2308332. doi: 10.1002/adma.202308332. Epub 2023 Nov 20.