PMID- 37836675
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20231020
IS  - 1420-3049 (Electronic)
IS  - 1420-3049 (Linking)
VI  - 28
IP  - 19
DP  - 2023 Sep 27
TI  - Ternary Organic Solar Cells by Small Amount of Efficient Light Absorption Polymer 
      PSEHTT as Third Component Materials.
LID - 10.3390/molecules28196832 [doi]
LID - 6832
AB  - We prepared ternary organic solar cells (OSCs) by incorporating the medium 
      wavelength absorption polymer PSEHTT into the PM6:L8-BO binary system. The power 
      conversion efficiency (PCE) is improved from 15.83% to 16.66%. Although the fill 
      factor (FF) is slightly reduced, the short-circuit current density (J(SC)) and 
      open-circuit voltage (V(OC)) are significantly increased at the same time. A 
      small amount of PSEHTT has a broad absorption spectrum in the short wavelength 
      region and has good compatibility with PM6, which is conducive to fine-tuning the 
      photon collection and improving the J(SC). In addition, the highest occupied 
      molecular orbital (HOMO) energy level of PSEHTT is deeper than that of PM6, which 
      broadens the optical bandgap. This study provides an effective method to 
      fabricate high-performance ternary OSCs by using a lower concentration of PSEHTT 
      with PM6 as a hybrid donor material, which ensures a better surface and bulk 
      morphology, improves photon collection, and broadens the optical bandgap.
FAU - Zhang, Han
AU  - Zhang H
AD  - Institute of Physics and Electronic Information, Yunnan Normal University, 
      Kunming 650500, China.
FAU - Jia, Songrui
AU  - Jia S
AUID- ORCID: 0000-0003-0895-7678
AD  - National and Local Joint Engineering Laboratory for Synthetic Technology of High 
      Performance Polymer, College of Chemistry, Jilin University, Changchun 130012, 
      China.
AD  - Engineering Research Center of Special Engineering Plastics, Ministry of 
      Education, College of Chemistry, Jilin University, Changchun 130012, China.
AD  - Key Laboratory of High Performance Plastics, Ministry of Education, College of 
      Chemistry, Jilin University, Changchun 130012, China.
FAU - Liu, Zhiyong
AU  - Liu Z
AD  - Institute of Physics and Electronic Information, Yunnan Normal University, 
      Kunming 650500, China.
AD  - Yunnan Key Laboratory of Optoelectronic Information Technology, Kunming 650500, 
      China.
AD  - Key Laboratory of Advanced Technique & Preparation for Renewable Energy 
      Materials, Ministry of Education, Yunnan Normal University, Kunming 650500, 
      China.
FAU - Chen, Zheng
AU  - Chen Z
AUID- ORCID: 0000-0002-5567-522X
AD  - National and Local Joint Engineering Laboratory for Synthetic Technology of High 
      Performance Polymer, College of Chemistry, Jilin University, Changchun 130012, 
      China.
AD  - Engineering Research Center of Special Engineering Plastics, Ministry of 
      Education, College of Chemistry, Jilin University, Changchun 130012, China.
AD  - Key Laboratory of High Performance Plastics, Ministry of Education, College of 
      Chemistry, Jilin University, Changchun 130012, China.
LA  - eng
GR  - 202305AF150012/Yunnan Expert Workstation/
GR  - 202205AF150008/Yunnan Expert Workstation/
GR  - 2022SCP005/Spring City Plan: the High-level Talent Promotion and Training Project 
      of Kunming/
GR  - 20220301018GX/Major Science and Technology Projects for Independent Innovation of 
      China FAW Group Co., Ltd./
PT  - Journal Article
DEP - 20230927
PL  - Switzerland
TA  - Molecules
JT  - Molecules (Basel, Switzerland)
JID - 100964009
SB  - IM
PMC - PMC10574318
OTO - NOTNLM
OT  - carrier recombination
OT  - exciton dissociation
OT  - light absorption
OT  - ternary OSCs
COIS- The authors declare no conflict of interest.
EDAT- 2023/10/14 10:45
MHDA- 2023/10/14 10:46
PMCR- 2023/09/27
CRDT- 2023/10/14 01:19
PHST- 2023/09/09 00:00 [received]
PHST- 2023/09/24 00:00 [revised]
PHST- 2023/09/26 00:00 [accepted]
PHST- 2023/10/14 10:46 [medline]
PHST- 2023/10/14 10:45 [pubmed]
PHST- 2023/10/14 01:19 [entrez]
PHST- 2023/09/27 00:00 [pmc-release]
AID - molecules28196832 [pii]
AID - molecules-28-06832 [pii]
AID - 10.3390/molecules28196832 [doi]
PST - epublish
SO  - Molecules. 2023 Sep 27;28(19):6832. doi: 10.3390/molecules28196832.