PMID- 37855722
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20231127
IS  - 1521-3773 (Electronic)
IS  - 1433-7851 (Linking)
VI  - 62
IP  - 49
DP  - 2023 Dec 4
TI  - Enhancing Local CO(2) Adsorption by L-histidine Incorporation for Selective 
      Formate Production Over the Wide Potential Window.
PG  - e202313522
LID - 10.1002/anie.202313522 [doi]
AB  - Electrochemical carbon dioxide reduction reaction (CO(2) RR) to produce valuable 
      chemicals is a promising pathway to alleviate the energy crisis and global 
      warming issues. However, simultaneously achieving high Faradaic efficiency (FE) 
      and current densities of CO(2) RR in a wide potential range remains as a huge 
      challenge for practical implements. Herein, we demonstrate that incorporating 
      bismuth-based (BH) catalysts with L-histidine, a common amino acid molecule of 
      proteins, is an effective strategy to overcome the inherent trade-off between the 
      activity and selectivity. Benefiting from the significantly enhanced CO(2) 
      adsorption capability and promoted electron-rich nature by L-histidine integrity, 
      the BH catalyst exhibits excellent FE(formate) in the unprecedented wide 
      potential windows (>90 % within -0.1--1.8 V and >95 % within -0.2--1.6 V versus 
      reversible hydrogen electrode, RHE). Excellent CO(2) RR performance can still be 
      achieved under the low-concentration CO(2) feeding (e.g., 20 vol.%). Besides, an 
      extremely low onset potential of -0.05 V(RHE) (close to the theoretical 
      thermodynamic potential of -0.02 V(RHE) ) was detected by in situ 
      ultraviolet-visible (UV-Vis) measurements, together with stable operation over 
      50 h with preserved FE(formate) of  approximately 95 % and high partial current density of 
      326.2 mA cm(-2) at -1.0 V(RHE) .
CI  - (c) 2023 Wiley-VCH GmbH.
FAU - Li, Yicheng
AU  - Li Y
AUID- ORCID: 0009-0000-7100-8542
AD  - School of Mechanical and Power Engineering, East China University of Science and 
      Technology, 130 Meilong Road, Shanghai, 200237, China.
FAU - Delmo, Ernest Pahuyo
AU  - Delmo EP
AUID- ORCID: 0000-0001-5913-7624
AD  - Department of Chemical and Biological Engineering, The Hong Kong University of 
      Science and Technology Clear Water Bay, Kowloon, Hong Kong, China.
FAU - Hou, Guoyu
AU  - Hou G
AUID- ORCID: 0000-0001-6811-8281
AD  - School of Mechanical and Power Engineering, East China University of Science and 
      Technology, 130 Meilong Road, Shanghai, 200237, China.
FAU - Cui, Xianglong
AU  - Cui X
AUID- ORCID: 0009-0001-2305-7646
AD  - School of Mechanical and Power Engineering, East China University of Science and 
      Technology, 130 Meilong Road, Shanghai, 200237, China.
FAU - Zhao, Ming
AU  - Zhao M
AUID- ORCID: 0000-0003-0127-1470
AD  - Department of Materials Science and Engineering, National University of 
      Singapore, Singapore, 117575, Singapore.
FAU - Tian, Zhihong
AU  - Tian Z
AUID- ORCID: 0000-0002-6377-376X
AD  - Engineering Research Center for Nanomaterials, Henan University, Kaifeng, 475004, 
      P. R. China.
FAU - Zhang, Yu
AU  - Zhang Y
AUID- ORCID: 0000-0001-8069-6826
AD  - School of Mechanical and Power Engineering, East China University of Science and 
      Technology, 130 Meilong Road, Shanghai, 200237, China.
FAU - Shao, Minhua
AU  - Shao M
AUID- ORCID: 0000-0003-4496-0057
AD  - Department of Chemical and Biological Engineering, The Hong Kong University of 
      Science and Technology Clear Water Bay, Kowloon, Hong Kong, China.
LA  - eng
GR  - 22109044/National Natural Science Foundation of China/
GR  - 22ZR1418500/Natural Science Foundation of Shanghai, China/
GR  - 16304821 and 16310419/Research Grant Council/
PT  - Journal Article
DEP - 20231031
PL  - Germany
TA  - Angew Chem Int Ed Engl
JT  - Angewandte Chemie (International ed. in English)
JID - 0370543
SB  - IM
OTO - NOTNLM
OT  - Bismuth-Based Catalyst
OT  - CO2 Adsorption
OT  - CO2 Reduction
OT  - Electrocatalysis
OT  - Formate
EDAT- 2023/10/19 12:47
MHDA- 2023/10/19 12:48
CRDT- 2023/10/19 10:12
PHST- 2023/09/11 00:00 [received]
PHST- 2023/10/19 12:48 [medline]
PHST- 2023/10/19 12:47 [pubmed]
PHST- 2023/10/19 10:12 [entrez]
AID - 10.1002/anie.202313522 [doi]
PST - ppublish
SO  - Angew Chem Int Ed Engl. 2023 Dec 4;62(49):e202313522. doi: 
      10.1002/anie.202313522. Epub 2023 Oct 31.