PMID- 37863214 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20231121 IS - 1879-1026 (Electronic) IS - 0048-9697 (Linking) VI - 907 DP - 2024 Jan 10 TI - Strength, porosity and life cycle analysis of geopolymer and hybrid cement mortars for sustainable construction. PG - 167839 LID - S0048-9697(23)06466-5 [pii] LID - 10.1016/j.scitotenv.2023.167839 [doi] AB - Owing to the application of industrial wastes, geopolymers are generally regarded as a sustainable alternative to traditional construction materials. However, their lack of adoption on the industrial scale demands detailed investigations. This study conducts a comparative analysis of the compressive strength of different geopolymer and hybrid cement mortars with varying proportions of sodium hydroxide (from 5 to 25 wt%) and ordinary Portland cement (OPC) (from 15 to 35 wt%), respectively. The porosity of all designed mixtures was also analyzed using X-ray computed tomography (XCT) and water absorption tests. ReCiPe 2016 Midpoint (H) method was used for the Life cycle analysis of the geopolymer and hybrid cement mortars. Multi-criteria decision making (MCDM) approach was used to assess the sustainability potential of the designed mixtures based on compressive strength, porosity and overall environmental impact. Experimental results revealed that the increase in sodium hydroxide in geopolymer mortars up to 15 wt% offered its maximum compressive strength. Superior compressive strength was obtained at 35 wt% of OPC in hybrid cement mortars due to the formation of more C-S-H, C-A-S-H and N-A-S-H gels which fill up the voids and pores. Analysis of the macro and micro-porosity revealed that hybrid cement mortars yield denser structure than geopolymer mortars. Life cycle analysis based on 8 distinct impact categories showed that hybrid cement mortars outperform the geopolymers in all impact categories except 'mineral resource scarcity'. However, the overall environmental impact assessment using the 'coefficient of performance' depicts that hybrid cement mortars offer a significantly lower environmental burden than geopolymers. MCDM analysis shows that hybrid cement mortar with 5 wt% of sodium hydroxide and 35 wt% of OPC is the best choice for construction applications. This idea of sustainable hybrid cement mortar will be helpful for the construction industry to limit the environmental impact without compromising their structural performance. CI - Copyright (c) 2023 Elsevier B.V. All rights reserved. FAU - Raza, Muhammad Huzaifa AU - Raza MH AD - Department of Industrial and Manufacturing Systems Engineering, The University of Hong Kong, Hong Kong. Electronic address: huzaifa@connect.hku.hk. FAU - Khan, Mahram AU - Khan M AD - Department of Civil Engineering, The University of Hong Kong, Hong Kong. Electronic address: mkhan@connect.hku.hk. FAU - Zhong, Ray Y AU - Zhong RY AD - Department of Industrial and Manufacturing Systems Engineering, The University of Hong Kong, Hong Kong. LA - eng PT - Journal Article DEP - 20231019 PL - Netherlands TA - Sci Total Environ JT - The Science of the total environment JID - 0330500 SB - IM OTO - NOTNLM OT - Environmental impact OT - Geopolymers OT - Hybrid cement mortars OT - Life cycle analysis OT - Sustainable construction COIS- Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. EDAT- 2023/10/21 05:42 MHDA- 2023/10/21 05:43 CRDT- 2023/10/20 19:28 PHST- 2023/07/01 00:00 [received] PHST- 2023/09/25 00:00 [revised] PHST- 2023/10/12 00:00 [accepted] PHST- 2023/10/21 05:43 [medline] PHST- 2023/10/21 05:42 [pubmed] PHST- 2023/10/20 19:28 [entrez] AID - S0048-9697(23)06466-5 [pii] AID - 10.1016/j.scitotenv.2023.167839 [doi] PST - ppublish SO - Sci Total Environ. 2024 Jan 10;907:167839. doi: 10.1016/j.scitotenv.2023.167839. Epub 2023 Oct 19.