PMID- 37866532
OWN - NLM
STAT- MEDLINE
DCOM- 20231123
LR  - 20231123
IS  - 1096-0953 (Electronic)
IS  - 0013-9351 (Linking)
VI  - 240
IP  - Pt 1
DP  - 2024 Jan 1
TI  - Fe and Zn co-doped carbon nanoparticles as peroxymonosulfate activator for 
      efficient 2,4-dichorophenol degradation.
PG  - 117313
LID - S0013-9351(23)02117-5 [pii]
LID - 10.1016/j.envres.2023.117313 [doi]
AB  - Iron-mediated activation of peroxymonosulfate (PMS) has been of great interest 
      for the effective removal of contaminants, but it still suffered from ineffective 
      metal redox cycle rate, which resulted in unsatisfactory catalytic efficiency. 
      Constructing bimetallic carbonaceous materials was effective way to improve the 
      catalytic performance of iron-based heterogeneous system. In this study, magnetic 
      bimetallic porous carbon composite (FZC(x)) was synthesized via Fe/Zn bi-MOFs 
      pyrolysis for 2,4-dichlorophenol (2,4-DCP) degradation by peroxymonosulfate. 
      Influences of different systems exhibited that 100% of 2,4-DCP was rapidly 
      degraded at the conditions of catalyst dosage = 0.1 g L(-1), PMS = 0.5 mM and 
      initial pH = 9.0 within 30 min. The as-prepared FZC(600) displayed excellent 
      reusability and stability. Quenching experiments and EPR analysis manifested that 
      SO(4)(.-) and (1)O(2) were primarily responsible for the rapid degradation of 
      2,4-DCP. Moreover, XPS, EPR and EIS was used to elaborate the bimetallic synergy 
      effect, proving that the introduction of zinc can effectively promote periodic 
      cycle of Fe(2+)/Fe(3+) and improve catalysts durability and reusability. These 
      findings highlighted the preparation of bimetallic based carbonaceous material 
      with excellent PMS activation ability to remove refractory organics from 
      wastewater and provided a depth insight into the promotion of bimetal synergy 
      between zinc and iron on PMS activation process.
CI  - Copyright (c) 2023 Elsevier Inc. All rights reserved.
FAU - Qiu, Xiaojie
AU  - Qiu X
AD  - School of Environmental Science and Engineering, Tianjin University, Tianjin, 
      300350, China.
FAU - Zhao, Yingxin
AU  - Zhao Y
AD  - School of Environmental Science and Engineering, Tianjin University, Tianjin, 
      300350, China. Electronic address: yingxinzhao@tju.edu.cn.
FAU - Jia, Zichen
AU  - Jia Z
AD  - School of Environmental Science and Engineering, Tianjin University, Tianjin, 
      300350, China.
FAU - Li, Chenxi
AU  - Li C
AD  - School of Environmental Science and Engineering, Tianjin University, Tianjin, 
      300350, China.
FAU - Jin, Ruotong
AU  - Jin R
AD  - School of Environmental Science and Engineering, Tianjin University, Tianjin, 
      300350, China.
FAU - Mutabazi, Emmanuel
AU  - Mutabazi E
AD  - School of Environmental Science and Engineering, Tianjin University, Tianjin, 
      300350, China.
LA  - eng
PT  - Journal Article
DEP - 20231020
PL  - Netherlands
TA  - Environ Res
JT  - Environmental research
JID - 0147621
RN  - 22047-43-4 (peroxymonosulfate)
RN  - E1UOL152H7 (Iron)
RN  - J41CSQ7QDS (Zinc)
RN  - 7440-44-0 (Carbon)
SB  - IM
MH  - *Iron
MH  - Zinc
MH  - Carbon
MH  - *Nanoparticles
OTO - NOTNLM
OT  - 2,4-Dichlorophenol degradation
OT  - Bimetallic catalyst
OT  - Peroxymonosulfate
OT  - Zinc doping
COIS- Declaration of competing interest The authors declare that they have no known 
      competing financial interests or personal relationships that could have appeared 
      to influence the work reported in this paper.
EDAT- 2023/10/23 00:45
MHDA- 2023/11/23 06:42
CRDT- 2023/10/22 19:30
PHST- 2023/08/10 00:00 [received]
PHST- 2023/09/17 00:00 [revised]
PHST- 2023/09/29 00:00 [accepted]
PHST- 2023/11/23 06:42 [medline]
PHST- 2023/10/23 00:45 [pubmed]
PHST- 2023/10/22 19:30 [entrez]
AID - S0013-9351(23)02117-5 [pii]
AID - 10.1016/j.envres.2023.117313 [doi]
PST - ppublish
SO  - Environ Res. 2024 Jan 1;240(Pt 1):117313. doi: 10.1016/j.envres.2023.117313. Epub 
      2023 Oct 20.