PMID- 37945966 OWN - NLM STAT- MEDLINE DCOM- 20231207 LR - 20231217 IS - 1614-7499 (Electronic) IS - 0944-1344 (Linking) VI - 30 IP - 57 DP - 2023 Dec TI - Heavy metal and persistent organic pollutant profile of sediments from marine protected areas: the northern Persian Gulf. PG - 120877-120891 LID - 10.1007/s11356-023-30688-1 [doi] AB - Marine protected areas (MPAs) are one of the policy tools to support marine biodiversity conservation and sustainable use of marine resources. The distribution, sources, and ecological risk assessment of persistent organic pollutants (POPs), including polycyclic aromatic hydrocarbon (PAHs), total petroleum hydrocarbons (TPHs), polychlorinated biphenyls (PCBs), and heavy metals (HMs) in sediments of MPAs in the northern Persian Gulf, were evaluated for the first time in this study. The Sigma(16)PAHs ranged from 4.65 to 20.86 mug/kg dry weight (dw). The molecular ratios and ring's pattern of PAHs suggested a mixed origin with a predominance of pyrogenic sources. The TPH concentration varied from 5.21 to 17.90 mug/g dw. Ecological risk assessment suggested that sediment samples in Bushehr Province's MPAs can be categorized as medium risk. The mean concentration of summation operator(18)PCB was 0.345-0.419 ng/g dw, and the main components correspond to PCB-77, PCB-105, PCB-81, PCB-101, and PCB-114. The mean concentration of As, Co, Cr, Ni, V, Mg, Pb, Zn, Cu, Al, and Fe varied from 4.79 to 9.69, 2-12, 39-142, 18-90, 15-58, 184-425, 7-45.9, 6-42.4, 4-20 mug/g dw, 0.75-4.12%, and 0.35-1.62%, respectively. Multivariate analysis, such as principal component analysis (PCA) and cluster analysis (CA), coupled with correlation coefficient analysis, was used to analyze the analytical data and to identify possible pollution sources. The results of this study provided the background information on the extent of POP contamination in the sediment and highlighted the need to further control pollution in MPAs. CI - (c) 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature. FAU - Ghaemi, Maryam AU - Ghaemi M AD - Iranian National Institute for Oceanography and Atmospheric Science, No. 3, Etemadzadeh St., Fatemi Ave., Tehran, 1411813389, Iran. maryam.ghaemy@gmail.com. FAU - Soleimani, Farshid AU - Soleimani F AD - Iranian National Institute for Oceanography and Atmospheric Science, No. 3, Etemadzadeh St., Fatemi Ave., Tehran, 1411813389, Iran. AD - Tobacco and Health Research Center, Hormozgan University of Medical Sciences, Bandar Abbas, Iran. FAU - Gholamipour, Sara AU - Gholamipour S AD - Iranian National Institute for Oceanography and Atmospheric Science, No. 3, Etemadzadeh St., Fatemi Ave., Tehran, 1411813389, Iran. LA - eng PT - Journal Article DEP - 20231110 PL - Germany TA - Environ Sci Pollut Res Int JT - Environmental science and pollution research international JID - 9441769 RN - 0 (Persistent Organic Pollutants) RN - 0 (Metals, Heavy) RN - 0 (Polycyclic Aromatic Hydrocarbons) RN - 0 (Water Pollutants, Chemical) SB - IM MH - Persistent Organic Pollutants MH - Geologic Sediments/chemistry MH - Indian Ocean MH - Environmental Monitoring MH - *Metals, Heavy/analysis MH - *Polycyclic Aromatic Hydrocarbons/analysis MH - *Water Pollutants, Chemical/analysis OTO - NOTNLM OT - Heavy metals OT - Marine protected area OT - Persian Gulf OT - Persistent organic pollutants OT - Polychlorinated biphenyls OT - Polycyclic aromatic hydrocarbon EDAT- 2023/11/10 00:44 MHDA- 2023/12/07 12:42 CRDT- 2023/11/09 23:52 PHST- 2023/06/24 00:00 [received] PHST- 2023/10/21 00:00 [accepted] PHST- 2023/12/07 12:42 [medline] PHST- 2023/11/10 00:44 [pubmed] PHST- 2023/11/09 23:52 [entrez] AID - 10.1007/s11356-023-30688-1 [pii] AID - 10.1007/s11356-023-30688-1 [doi] PST - ppublish SO - Environ Sci Pollut Res Int. 2023 Dec;30(57):120877-120891. doi: 10.1007/s11356-023-30688-1. Epub 2023 Nov 10.