PMID- 37955734 OWN - NLM STAT- MEDLINE DCOM- 20231218 LR - 20231227 IS - 1614-7499 (Electronic) IS - 0944-1344 (Linking) VI - 30 IP - 58 DP - 2023 Dec TI - Residue dissipation dynamics and dietary risk assessment of emamectin benzoate, chlorantraniliprole, chlorfenapyr, and lufenuron in cabbage. PG - 121748-121758 LID - 10.1007/s11356-023-30919-5 [doi] AB - Emamectin benzoate (EB), chlorantraniliprole (CTP), chlorfenapyr (CFP), and lufenuron (LFR) are widely used to control Spodoptera exigua on cabbage. This study is aimed at establishing a universal, sensitive, accurate, and efficient method for the determination of these pesticide residues in cabbage using QuEChERS pretreatment combined with ultra-performance liquid chromatography or gas chromatography-tandem mass spectrometry (UPLC‒MS/MS or GC‒MS/MS). The recoveries of these pesticides (containing metabolites) in cabbage detected by the optimized method ranged between 80.9% and 99.9%, with relative standard deviations (RSDs) of 0.164-12.5%. The limit of quantification (LOQ) of the four pesticides was determined to be 0.01 mg/kg. The standard curve, accuracy, precision, and LOQ of the analysis method all met the requirements of pesticide residue detection. The optimized method was used to detect the dissipation dynamics and terminal residues in 12 regions. The dissipation half-lives of CTP, CFP, and LFR were 3.35-7.01 d, 2.29-4.75 d, and 3.24-6.80 d, respectively. The terminal residues of all these pesticides were below the maximum residue limits (MRLs). The dietary risk assessment indicated that the dietary risk probabilities for EB, CTP, CFP, and LFR were all less than 1 and were within the acceptable range. This study provides a comprehensive assessment of the residues and dietary risks of EB, CTP, CFP, and LFR for the scientific use of pesticides. CI - (c) 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature. FAU - Wang, Xiaoyao AU - Wang X AD - Department of Nutrition and Food Hygiene, School of Public Health, Shandong First Medical University & Shandong Academy of Medical Sciences, Jinan, 250021, Shandong, China. AD - Shandong Provincial Key Laboratory for Biology of Vegetable Diseases and Insect Pests, College of Plant Protection, Shandong Agricultural University, Tai'an, 271018, Shandong, China. FAU - Hu, Shuai AU - Hu S AD - Shandong Provincial Key Laboratory for Biology of Vegetable Diseases and Insect Pests, College of Plant Protection, Shandong Agricultural University, Tai'an, 271018, Shandong, China. FAU - Meng, Lingtao AU - Meng L AD - Shandong Binnong Technology Co., Ltd., Binzhou, 256600, Shandong, China. FAU - Wang, Kai AU - Wang K AD - Shandong Binnong Technology Co., Ltd., Binzhou, 256600, Shandong, China. FAU - Zhang, Xianxia AU - Zhang X AD - Research Center of Pesticide Environmental Toxicology, Shandong Agricultural University, Tai'an, 271018, Shandong, China. FAU - Li, Ke AU - Li K AD - Research Center of Pesticide Environmental Toxicology, Shandong Agricultural University, Tai'an, 271018, Shandong, China. FAU - Wang, Ning AU - Wang N AD - Department of Nutrition and Food Hygiene, School of Public Health, Shandong First Medical University & Shandong Academy of Medical Sciences, Jinan, 250021, Shandong, China. FAU - Zou, Nan AU - Zou N AD - Shandong Provincial Key Laboratory for Biology of Vegetable Diseases and Insect Pests, College of Plant Protection, Shandong Agricultural University, Tai'an, 271018, Shandong, China. AD - Research Center of Pesticide Environmental Toxicology, Shandong Agricultural University, Tai'an, 271018, Shandong, China. FAU - Xu, Yue AU - Xu Y AD - Shandong Provincial Key Laboratory for Biology of Vegetable Diseases and Insect Pests, College of Plant Protection, Shandong Agricultural University, Tai'an, 271018, Shandong, China. AD - Research Center of Pesticide Environmental Toxicology, Shandong Agricultural University, Tai'an, 271018, Shandong, China. FAU - Li, Beixing AU - Li B AD - Shandong Provincial Key Laboratory for Biology of Vegetable Diseases and Insect Pests, College of Plant Protection, Shandong Agricultural University, Tai'an, 271018, Shandong, China. AD - Research Center of Pesticide Environmental Toxicology, Shandong Agricultural University, Tai'an, 271018, Shandong, China. FAU - Mu, Wei AU - Mu W AD - Shandong Provincial Key Laboratory for Biology of Vegetable Diseases and Insect Pests, College of Plant Protection, Shandong Agricultural University, Tai'an, 271018, Shandong, China. AD - Research Center of Pesticide Environmental Toxicology, Shandong Agricultural University, Tai'an, 271018, Shandong, China. FAU - Pang, Xiuyu AU - Pang X AD - Department of Nutrition and Food Hygiene, School of Public Health, Shandong First Medical University & Shandong Academy of Medical Sciences, Jinan, 250021, Shandong, China. pangxy123@163.com. LA - eng GR - 2022BBF02012/Education Department of Ningxia Hui Autonomous Region/ GR - 2021NS315/Science and Technology Innovation Development Project of Tai'an/ GR - YDZX2022155/the Central Government Guides of the Local Science and Technology Development Fund Projects/ GR - S202210434018S/Provincial Innovation and Entrepreneurship Training Program for College Students in Shandong Province/ GR - S202210439018/Provincial Innovation and Entrepreneurship Training Program for College Students in Shandong Province/ GR - S202210439030/Provincial Innovation and Entrepreneurship Training Program for College Students in Shandong Province/ GR - 2022QNRC001/Young Elite Scientists Sponsorship Program by Tianjin/ PT - Journal Article DEP - 20231113 PL - Germany TA - Environ Sci Pollut Res Int JT - Environmental science and pollution research international JID - 9441769 RN - HVM3G4A01W (emamectin benzoate) RN - NWI20P05EB (chlorfenapyr) RN - 622AK9DH9G (chlorantranilipole) RN - 1R754M4918 (fluphenacur) RN - 0 (Pesticides) RN - 0 (Pesticide Residues) SB - IM MH - *Brassica/chemistry MH - Tandem Mass Spectrometry MH - Chromatography, Liquid MH - Gas Chromatography-Mass Spectrometry MH - *Pesticides/analysis MH - *Pesticide Residues/analysis MH - Risk Assessment OTO - NOTNLM OT - Cabbage OT - Dietary risk assessment OT - GC‒MS/MS OT - Pesticide residue OT - UPLC‒MS/MS EDAT- 2023/11/13 12:45 MHDA- 2023/12/18 06:42 CRDT- 2023/11/13 11:08 PHST- 2023/07/19 00:00 [received] PHST- 2023/11/02 00:00 [accepted] PHST- 2023/12/18 06:42 [medline] PHST- 2023/11/13 12:45 [pubmed] PHST- 2023/11/13 11:08 [entrez] AID - 10.1007/s11356-023-30919-5 [pii] AID - 10.1007/s11356-023-30919-5 [doi] PST - ppublish SO - Environ Sci Pollut Res Int. 2023 Dec;30(58):121748-121758. doi: 10.1007/s11356-023-30919-5. Epub 2023 Nov 13.