PMID- 37957886 OWN - NLM STAT- MEDLINE DCOM- 20240131 LR - 20240206 IS - 1522-7243 (Electronic) IS - 1522-7235 (Linking) VI - 39 IP - 1 DP - 2024 Jan TI - Synthesis of a water-stable CsPbBr(3) perovskite for selective detection of mercury ion in water. PG - e4615 LID - 10.1002/bio.4615 [doi] AB - By using the method of low-temperature crystallization, CsPbBr(3) perovskite nanocrystals (PNCs) coated with trifluoroacetyl lysine (Tfa-Lys) and oleamine (Olam) were synthesized in aqueous solution. The structure of the CsPbBr(3) PNCs was characterized by many methods, such as ultraviolet (UV)-visible absorption spectrophotometer, fluorescence spectrophotometer, transmission electron microscopy (TEM), and X-ray diffraction (XRD) pattern. The fluorescence emission of the CsPbBr(3) PNCs is stable in water for about 1 day at room temperature. It was also found that the fluorescence of the PNCs could be obviously and selectively quenched after the addition of mercury ion (Hg(2+) ), allowing a visual detection of Hg(2+) by the naked eye under UV light illumination. The fluorescence quenching rate (I(0) /I) has a good linear relationship with the addition of Hg(2+) in the concentration range 0.075 to 1.5 mg/L, with a correlation coefficient (R(2) ) of 0.997, and limit of detection of 0.046 mg/L. The fluorescence quenching mechanism of the PNCs was determined by the fluorescence lifetime and X-ray photoelectron spectroscopy (XPS) of the PNCs. Overall, the synthesis method for CsPbBr(3) PNCs is simple and rapid, and the as-prepared PNCs are stable in water that could be conveniently used for selective detection of Hg(2+) in the water environment. CI - (c) 2023 John Wiley & Sons Ltd. FAU - Huang, Jingtao AU - Huang J AD - Key Laboratory of Medicinal Chemistry for Natural Resource (Yunnan University), Ministry of Education, National Demonstration Center for Experimental Chemistry and Chemical Engineering Education (Yunnan University), School of Chemical Science and Technology, Yunnan University, Kunming, China. FAU - Hu, Yi-Lin AU - Hu YL AD - Key Laboratory of Medicinal Chemistry for Natural Resource (Yunnan University), Ministry of Education, National Demonstration Center for Experimental Chemistry and Chemical Engineering Education (Yunnan University), School of Chemical Science and Technology, Yunnan University, Kunming, China. FAU - Liu, Jin-Zhou AU - Liu JZ AD - Key Laboratory of Medicinal Chemistry for Natural Resource (Yunnan University), Ministry of Education, National Demonstration Center for Experimental Chemistry and Chemical Engineering Education (Yunnan University), School of Chemical Science and Technology, Yunnan University, Kunming, China. FAU - Zhang, Hai-Chi AU - Zhang HC AD - Key Laboratory of Medicinal Chemistry for Natural Resource (Yunnan University), Ministry of Education, National Demonstration Center for Experimental Chemistry and Chemical Engineering Education (Yunnan University), School of Chemical Science and Technology, Yunnan University, Kunming, China. FAU - Cao, Qiu-E AU - Cao QE AD - Key Laboratory of Medicinal Chemistry for Natural Resource (Yunnan University), Ministry of Education, National Demonstration Center for Experimental Chemistry and Chemical Engineering Education (Yunnan University), School of Chemical Science and Technology, Yunnan University, Kunming, China. FAU - Li, Rong Sheng AU - Li RS AD - Key Laboratory of Medicinal Chemistry for Natural Resource (Yunnan University), Ministry of Education, National Demonstration Center for Experimental Chemistry and Chemical Engineering Education (Yunnan University), School of Chemical Science and Technology, Yunnan University, Kunming, China. FAU - Ling, Jian AU - Ling J AUID- ORCID: 0000-0003-3744-9410 AD - Key Laboratory of Medicinal Chemistry for Natural Resource (Yunnan University), Ministry of Education, National Demonstration Center for Experimental Chemistry and Chemical Engineering Education (Yunnan University), School of Chemical Science and Technology, Yunnan University, Kunming, China. LA - eng GR - 21565030/National Natural Science Foundation of China/ GR - 22164020/National Natural Science Foundation of China/ GR - 22304152/National Natural Science Foundation of China/ PT - Journal Article DEP - 20231113 PL - England TA - Luminescence JT - Luminescence : the journal of biological and chemical luminescence JID - 100889025 RN - 059QF0KO0R (Water) RN - 12194-71-7 (perovskite) RN - FXS1BY2PGL (Mercury) RN - 0 (Oxides) RN - D1JT611TNE (Titanium) RN - 0 (Calcium Compounds) SB - IM MH - Water/chemistry MH - *Mercury MH - Oxides/chemistry MH - *Nanoparticles/chemistry MH - *Titanium MH - *Calcium Compounds OTO - NOTNLM OT - CsPbBr3 OT - fluorescence OT - mercury ion OT - perovskite nanocrystals OT - water-stable EDAT- 2023/11/14 06:42 MHDA- 2024/01/31 06:42 CRDT- 2023/11/14 01:12 PHST- 2023/09/21 00:00 [revised] PHST- 2023/08/18 00:00 [received] PHST- 2023/10/13 00:00 [accepted] PHST- 2024/01/31 06:42 [medline] PHST- 2023/11/14 06:42 [pubmed] PHST- 2023/11/14 01:12 [entrez] AID - 10.1002/bio.4615 [doi] PST - ppublish SO - Luminescence. 2024 Jan;39(1):e4615. doi: 10.1002/bio.4615. Epub 2023 Nov 13.