PMID- 37999556 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20231127 IS - 2305-6304 (Electronic) IS - 2305-6304 (Linking) VI - 11 IP - 11 DP - 2023 Nov 6 TI - Potential Linkage between Heavy Metal Pollution Risk Assessment and Dissolved Organic Matter Spectra in the WWTPs-River Integrated Area-Case Study from Ashi River. LID - 10.3390/toxics11110904 [doi] LID - 904 AB - Direct sewage discharge can cause severe damage to the water environment of the river. However, the impacts of dissolved organic matter (DOM) in the discharge on the original pattern of DOM and the distribution of heavy metals (HMs) in the river are little known. How to monitor such areas in a long-term and systematic manner also needs to be urgently addressed. In this paper, we characterized the DOM of the sediments in the WWTPs (wastewater treatment plants)-river integrated zone by ultraviolet-visible absorption spectroscopy (UV-vis), three-dimensional excitation-emission matrix (3D-EEM) combined with parallel factor (PARAFAC) method. The effects of WWTP on receiving waters were investigated, and the potential link between DOM and HM pollution was explored. Hg (I(geo): 3.94 +/- 0.65; EF: 44.83 +/- 31.11), Cd (I(geo): 1.81 +/- 0.69; EF: 8.02 +/- 2.97), Cu (I(geo): 1.61 +/- 0.83; EF: 6.85 +/- 2.37), Zn (I(geo): 1.55 +/- 0.54; EF: 7.24 +/- 3.58), and Ni (I(geo): 1.46 +/- 0.56; EF: 6.12 +/- 1.99) in rivers were the primary risk sources of HM. The combined pollution risk indicates that the WWTPs-river integrated area is in a high pollution risk state. Moreover, alpha(254) has a significant correlation with pollution indicators and can be used as a proxy indicator. These results help to understand better the impact of WWTPs on receiving water bodies and the potential connection between DOM and HM pollution and provide new ideas for monitoring the water environment in highly polluted areas. FAU - Dai, Taoyan AU - Dai T AUID- ORCID: 0000-0002-4749-2407 AD - School of Water Resources and Electricity, Heilongjiang University, Harbin 150080, China. FAU - Li, Zhijun AU - Li Z AD - School of Water Resources and Electricity, Heilongjiang University, Harbin 150080, China. FAU - Wang, Liquan AU - Wang L AD - School of Water Resources and Electricity, Heilongjiang University, Harbin 150080, China. FAU - Li, Tienan AU - Li T AD - Heilongjiang Province Hydraulic Research Institute, Harbin 150080, China. FAU - Qiu, Pengpeng AU - Qiu P AD - Heilongjiang Province Hydraulic Research Institute, Harbin 150080, China. FAU - Wang, Jun AU - Wang J AD - Heilongjiang Province Hydraulic Research Institute, Harbin 150080, China. FAU - Song, Haotian AU - Song H AD - School of Water Resources and Electricity, Heilongjiang University, Harbin 150080, China. LA - eng GR - YJSCX2022-255HLJU/Innovative Research Program for Graduate Students of Heilongjiang University/ GR - GZ20220138/Heilongjiang Key Research and Development Program, Guidance Category/ GR - GZ20210061/Heilongjiang Key Research and Development Program, Guidance Category/ GR - ES202116/Open Project of State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology/ PT - Journal Article DEP - 20231106 PL - Switzerland TA - Toxics JT - Toxics JID - 101639637 PMC - PMC10674235 OTO - NOTNLM OT - WWTPs-river integrated area OT - dissolved organic matter OT - environmental risk assessment OT - human activities OT - parallel factor analysis OT - spectral index COIS- The authors declare no conflict of interest. The funders had no role in the design of the study; in the collection, analyses, or interpretation of data; in the writing of the manuscript; or in the decision to publish the results. EDAT- 2023/11/24 12:41 MHDA- 2023/11/24 12:42 PMCR- 2023/11/06 CRDT- 2023/11/24 09:54 PHST- 2023/10/16 00:00 [received] PHST- 2023/10/30 00:00 [revised] PHST- 2023/11/02 00:00 [accepted] PHST- 2023/11/24 12:42 [medline] PHST- 2023/11/24 12:41 [pubmed] PHST- 2023/11/24 09:54 [entrez] PHST- 2023/11/06 00:00 [pmc-release] AID - toxics11110904 [pii] AID - toxics-11-00904 [pii] AID - 10.3390/toxics11110904 [doi] PST - epublish SO - Toxics. 2023 Nov 6;11(11):904. doi: 10.3390/toxics11110904.