PMID- 38006871 OWN - NLM STAT- MEDLINE DCOM- 20240105 LR - 20240105 IS - 1879-3363 (Electronic) IS - 0025-326X (Linking) VI - 198 DP - 2024 Jan TI - Spatiotemporal distribution, source analysis and ecological risk assessment of polychlorinated biphenyls (PCBs) in the Bohai Bay, China. PG - 115780 LID - S0025-326X(23)01215-8 [pii] LID - 10.1016/j.marpolbul.2023.115780 [doi] AB - As a class of persistent organic pollutants (POPs), the spatial and temporal distribution of polychlorinated biphenyls (PCBs) in seawater is important for environmental assessment. Surface water samples were collected from 35 stations during summer and 36 stations during autumn of 2020 in the Bohai Bay. The concentration, composition, distribution and sources of PCBs were analyzed to assess the ecological impact of PCBs. The average concentration of summation operator(18)PCBs was 124.6 ng/L (range of 28.1-445.5 ng/L) in summer and 122.8 ng/L (range of 21.0-581.4 ng/L) in autumn. PCBs in surface seawater of the Bohai Bay showed high near-shore and low far-shore characteristics, indicating the serious influence of land-based sources such as port activities and river inputs. Proportion analysis showed that Tetra-PCBs and Penta-PCBs were the major constituents in most stations. It was assessed as moderate and high risk (MRQ > 0.1) by mixture risk quotient (MRQ) and concentration addition (CA) model in surface seawater of the Bohai Bay. Principal component analysis (PCA) was used to explain the sources of PCBs in the Bohai Bay. PCBs in the Bohai Bay may come from commercial PCBs and their incineration products, municipal landfills, wood and coal combustion, and industrial activities, etc. CI - Copyright (c) 2023 Elsevier Ltd. All rights reserved. FAU - Jiang, Shan AU - Jiang S AD - Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, Qingdao 266100, China. FAU - Wan, Mengmeng AU - Wan M AD - Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, Qingdao 266100, China. FAU - Lin, Kun AU - Lin K AD - Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, Qingdao 266100, China. FAU - Chen, Yanshan AU - Chen Y AD - Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, Qingdao 266100, China. FAU - Wang, Rui AU - Wang R AD - Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, Qingdao 266100, China; Battery Technology Company, Wanhua Chemical Group Co., Ltd. Yantai 265503, China. FAU - Tan, Liju AU - Tan L AD - Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, Qingdao 266100, China. FAU - Wang, Jiangtao AU - Wang J AD - Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, Qingdao 266100, China. Electronic address: jtwang@ouc.edu.cn. LA - eng PT - Journal Article DEP - 20231124 PL - England TA - Mar Pollut Bull JT - Marine pollution bulletin JID - 0260231 RN - DFC2HB4I0K (Polychlorinated Biphenyls) RN - 0 (Water Pollutants, Chemical) SB - IM MH - *Polychlorinated Biphenyls/analysis MH - Geologic Sediments/analysis MH - Bays MH - *Water Pollutants, Chemical/analysis MH - Environmental Monitoring MH - China MH - Risk Assessment OTO - NOTNLM OT - Bohai Bay OT - Ecological risk assessment OT - PCBs OT - Source analysis OT - Spatiotemporal distribution COIS- Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. EDAT- 2023/11/26 07:44 MHDA- 2024/01/05 06:43 CRDT- 2023/11/25 18:13 PHST- 2023/07/13 00:00 [received] PHST- 2023/11/02 00:00 [revised] PHST- 2023/11/11 00:00 [accepted] PHST- 2024/01/05 06:43 [medline] PHST- 2023/11/26 07:44 [pubmed] PHST- 2023/11/25 18:13 [entrez] AID - S0025-326X(23)01215-8 [pii] AID - 10.1016/j.marpolbul.2023.115780 [doi] PST - ppublish SO - Mar Pollut Bull. 2024 Jan;198:115780. doi: 10.1016/j.marpolbul.2023.115780. Epub 2023 Nov 24.