PMID- 38013435
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20231212
IS  - 1520-6882 (Electronic)
IS  - 0003-2700 (Linking)
VI  - 95
IP  - 49
DP  - 2023 Dec 12
TI  - Integrating Intelligent Logic Gate Dual-Nanozyme Cascade Fluorescence Capillary 
      Imprinted Sensors for Ultrasensitive Simultaneous Detection of 
      2,4-Dichlorophenoxyacetic Acid and 2,4-Dichlorophenol.
PG  - 18139-18148
LID - 10.1021/acs.analchem.3c03571 [doi]
AB  - Herein, a dual-nanozyme cascade catalysis triemission fluorescence capillary 
      imprinted sensor integrated with intelligent logic gates was constructed for 
      simultaneous detection of 2,4-dichlorophenoxyacetic acid (2,4-DA) and 
      2,4-dichlorophenol (2,4-DCP). The novel nanozyme fluorescence organic framework 
      (Bi, Co-MOF) was grafted on the surface of Fe(3)O(4) modified with histidine to 
      form a nanozyme composite (FBM) with dual-enzyme activity, which was imprinted 
      with 2,4-DA to prepare a fluorescence molecularly imprinted polymer (FBM@MIP). 
      Carbon dots (CDs) coupling with FBM@MIP (FBM@MIP/CDs) was inhaled into a 
      capillary to construct a dual-nanozyme capillary imprinted sensor directly. The 
      FBM@MIP/CDs capillary sensor realized to detect 2,4-DA and 2,4-DCP simultaneously 
      within a linear concentration range of 1.0 x 10(-12)-1.2 x 10(-9) M and 1.0 x 
      10(-12)-4.8 x 10(-9) M with the detection limit of 0.75 and 0.68 pM, 
      respectively. Interestingly, a smartphone-assisted portable capillary 
      fluorescence intelligent sensing platform was developed that can detect 2,4-DA 
      and 2,4-DCP visually without tedious operations such as soaking and drying. 
      Combined with a smartphone, the linear relationships between RGB ratios and 
      concentrations of 2,4-DA and 2,4-DCP were established with the detection limit of 
      0.93 and 0.81 pM, respectively. The integrated logic gates provided a promising 
      way for intelligent sensing of multiple targets simultaneously, which provided a 
      new strategy for ultrasensitive simultaneous detection of multiple pollutants 
      with a microvolume (18 muL/time) in complex environments.
FAU - Chen, Yu
AU  - Chen Y
AD  - College of Biological and Chemical Engineering, Changsha University, Changsha 
      410022, PR China.
AD  - College of Chemistry and Chemical Engineering, Jishou University, Jishou,Hunan 
      416000, China.
FAU - Tang, Kangling
AU  - Tang K
AD  - College of Biological and Chemical Engineering, Changsha University, Changsha 
      410022, PR China.
AD  - College of Chemistry and Chemical Engineering, Jishou University, Jishou,Hunan 
      416000, China.
FAU - Zhou, Qin
AU  - Zhou Q
AD  - College of Biological and Chemical Engineering, Changsha University, Changsha 
      410022, PR China.
AD  - College of Chemistry and Chemical Engineering, Jishou University, Jishou,Hunan 
      416000, China.
FAU - Wang, Xiangni
AU  - Wang X
AD  - College of Biological and Chemical Engineering, Changsha University, Changsha 
      410022, PR China.
AD  - College of Chemistry and Chemical Engineering, Jishou University, Jishou,Hunan 
      416000, China.
FAU - Wang, Ruoyan
AU  - Wang R
AD  - College of Biological and Chemical Engineering, Changsha University, Changsha 
      410022, PR China.
AD  - College of Chemistry and Chemical Engineering, Jishou University, Jishou,Hunan 
      416000, China.
FAU - Zhang, Zhaohui
AU  - Zhang Z
AUID- ORCID: 0000-0002-7318-6630
AD  - College of Biological and Chemical Engineering, Changsha University, Changsha 
      410022, PR China.
AD  - College of Chemistry and Chemical Engineering, Jishou University, Jishou,Hunan 
      416000, China.
AD  - State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, 
      Changsha 410082, PR China.
LA  - eng
PT  - Journal Article
DEP - 20231128
PL  - United States
TA  - Anal Chem
JT  - Analytical chemistry
JID - 0370536
SB  - IM
EDAT- 2023/11/28 06:42
MHDA- 2023/11/28 06:43
CRDT- 2023/11/28 03:39
PHST- 2023/11/28 06:43 [medline]
PHST- 2023/11/28 06:42 [pubmed]
PHST- 2023/11/28 03:39 [entrez]
AID - 10.1021/acs.analchem.3c03571 [doi]
PST - ppublish
SO  - Anal Chem. 2023 Dec 12;95(49):18139-18148. doi: 10.1021/acs.analchem.3c03571. 
      Epub 2023 Nov 28.