PMID- 38033158
OWN - NLM
STAT- MEDLINE
DCOM- 20231216
LR  - 20240208
IS  - 1526-4602 (Electronic)
IS  - 1525-7797 (Linking)
VI  - 24
IP  - 12
DP  - 2023 Dec 11
TI  - Synthesis and Properties of Polybutylene (Succinate)-b-poly(dimethylsiloxane) 
      with Unprecedented Combined Performance and Functions.
PG  - 5951-5963
LID - 10.1021/acs.biomac.3c00956 [doi]
AB  - The excellent combined properties of poly(butylene succinate) (PBS) make it a 
      promising biodegradable plastic. However, the lack of functionality and low 
      impact strength limit its application. Poly(dimethylsiloxane) (PDMS) was 
      introduced to prepare new high-performance and functional poly(butylene 
      succinate)-b-poly(dimethylsiloxane) (PBS-b-PDMS) in this work. The resulting 
      PBS-b-PDMS was found to possess high molecular weight, narrow molecular weight 
      distribution, and excellent combined performance. PBS-b-PDMS had good thermal 
      properties. The decomposition temperature of 5% weight loss (T(5%)) increased 
      from 324 to 344  degrees C, and the temperatures at the maximum weight loss rate (T(max)) 
      values increased from 385.1 to 396.7  degrees C. The impact strength increased 
      significantly from 7.8 kJ/m(2) of PBS to 53.9 kJ/m(2) of PBS-b-PDMS. As the PDMS 
      block endows copolymers with low surface energy and good liquid resistance, 
      PBS-b-PDMS has excellent antismudge, self-cleaning, and solvent resistance. 
      Finally, to minimize the surface energy, PDMS blocks preferentially enrich the 
      surface, which imparts the polymers with self-cleaning properties.
FAU - Zhou, Tianbo
AU  - Zhou T
AD  - School of Textile Science and Engineering, Tiangong University, Tianjin 300387, 
      P. R. China.
FAU - Liu, Guoming
AU  - Liu G
AUID- ORCID: 0000-0003-2808-2661
AD  - Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of 
      Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences, 
      Beijing 100190, P. R. China.
FAU - Wang, Ming
AU  - Wang M
AD  - Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of 
      Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences, 
      Beijing 100190, P. R. China.
FAU - Liu, Yi
AU  - Liu Y
AUID- ORCID: 0000-0001-7626-0026
AD  - School of Textile Science and Engineering, Tiangong University, Tianjin 300387, 
      P. R. China.
FAU - Zheng, Liuchun
AU  - Zheng L
AUID- ORCID: 0000-0002-6538-4805
AD  - School of Textile Science and Engineering, Tiangong University, Tianjin 300387, 
      P. R. China.
AD  - School of Chemical Engineering and Technology, Xinjiang University, Urumqi 
      830046, P. R. China.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20231130
PL  - United States
TA  - Biomacromolecules
JT  - Biomacromolecules
JID - 100892849
RN  - 0 (bionole)
RN  - 63148-62-9 (baysilon)
RN  - 0 (Biocompatible Materials)
RN  - 9003-29-6 (polybutene)
RN  - 0 (Polymers)
RN  - 0 (Succinates)
SB  - IM
MH  - Humans
MH  - *Biocompatible Materials
MH  - *Polymers
MH  - Succinates
MH  - Weight Loss
EDAT- 2023/11/30 18:45
MHDA- 2023/12/17 09:43
CRDT- 2023/11/30 14:23
PHST- 2023/12/17 09:43 [medline]
PHST- 2023/11/30 18:45 [pubmed]
PHST- 2023/11/30 14:23 [entrez]
AID - 10.1021/acs.biomac.3c00956 [doi]
PST - ppublish
SO  - Biomacromolecules. 2023 Dec 11;24(12):5951-5963. doi: 10.1021/acs.biomac.3c00956. 
      Epub 2023 Nov 30.