PMID- 38176250
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20240126
IS  - 1873-3573 (Electronic)
IS  - 0039-9140 (Linking)
VI  - 270
DP  - 2024 Apr 1
TI  - Rapid and in-situ preparation COFs coated capillary by adsorption method for the 
      separation and determination of phthalate ester using CEC.
PG  - 125617
LID - S0039-9140(23)01368-1 [pii]
LID - 10.1016/j.talanta.2023.125617 [doi]
AB  - As a novel class of stationary phase materials, covalent organic frameworks 
      (COFs) have shown great promise in open-tubular capillary electrochromatography. 
      However, the current preparation of COFs coating capillaries heavily relies on 
      tedious and time-consuming covalent bond methods. In this work, a novel, simple 
      and rapid adsorption method was developed for fabrication of TPB-DMTP COF 
      (fabricated from 1,3,5-tris(4-aminophenyl)benzene (TPB) and 
      2,5-dimethoxyterephthalaldehyde (DMTP)) coated capillary. Due to the 
      crystallization process of the COF is greatly shortened because pre-modification 
      capillary does not require silane coupling agent, this method enables the rapid 
      preparation of COFs-coated capillaries. The organic molecular building units only 
      need 25 min to form a stable COFs coating on the inner wall of a capillary by 
      this method. To our knowledge, this is the shortest method for preparing COFs 
      coated capillary up to now. The performance of the TPB-DMTP COF coated capillary 
      was evaluated by using phthalate esters as model analytes. The results 
      demonstrated that the TPB-DMTP COF coated capillary has excellent repeatability 
      and stability. The relative standard deviations (RSDs) of the analyte's retention 
      time of intra-day, inter-day and column-to-column were in the range of 
      0.05 %-0.27 %, 0.31 %-0.63 % and 0.31 %-0.88 %, respectively. And, no significant 
      changes were observed in separation efficiency and retention time after over 200 
      runs. Finally, the TPB-DMTP COF coated capillary was applied for the 
      determination of phthalates in marketed plastic bag and the recovery ranged from 
      88.0 % to 114.0 %.
CI  - Copyright (c) 2024 Elsevier B.V. All rights reserved.
FAU - Wang, Guoxiu
AU  - Wang G
AD  - State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 
      730000, China; Beijing Products Quality Supervision and Inspection Institute, 
      Beijing 101300, China. Electronic address: wangguoxiu2023@163.com.
FAU - Chen, Yonglei
AU  - Chen Y
AD  - State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 
      730000, China. Electronic address: chyl@lzu.edu.cn.
FAU - Lv, Wenjuan
AU  - Lv W
AD  - State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 
      730000, China. Electronic address: lvwenj@lzu.edu.cn.
FAU - Jia, Zhe
AU  - Jia Z
AD  - State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 
      730000, China. Electronic address: 12337063@zju.edu.cn.
FAU - Chen, Hongli
AU  - Chen H
AD  - State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 
      730000, China. Electronic address: hlchen@lzu.edu.cn.
FAU - Chen, Xingguo
AU  - Chen X
AD  - State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 
      730000, China; College of Chemistry and Chemical Engineering, Lanzhou University, 
      Lanzhou 730000, China. Electronic address: chenxg@lzu.edu.cn.
LA  - eng
PT  - Journal Article
DEP - 20231230
PL  - Netherlands
TA  - Talanta
JT  - Talanta
JID - 2984816R
SB  - IM
OTO - NOTNLM
OT  - Open-tubular capillary electrochromatography covalent organic frameworks 
      adsorption method in situ preparation
COIS- Declaration of Competing interest The authors declare that they have no conflict 
      of interest or personal relationships that could have appeared to influence the 
      work reported here.
EDAT- 2024/01/05 00:42
MHDA- 2024/01/05 00:43
CRDT- 2024/01/04 18:10
PHST- 2023/11/01 00:00 [received]
PHST- 2023/12/28 00:00 [revised]
PHST- 2023/12/29 00:00 [accepted]
PHST- 2024/01/05 00:43 [medline]
PHST- 2024/01/05 00:42 [pubmed]
PHST- 2024/01/04 18:10 [entrez]
AID - S0039-9140(23)01368-1 [pii]
AID - 10.1016/j.talanta.2023.125617 [doi]
PST - ppublish
SO  - Talanta. 2024 Apr 1;270:125617. doi: 10.1016/j.talanta.2023.125617. Epub 2023 Dec 
      30.