PMID- 38219323
OWN - NLM
STAT- MEDLINE
DCOM- 20240226
LR  - 20240226
IS  - 1873-3573 (Electronic)
IS  - 0039-9140 (Linking)
VI  - 271
DP  - 2024 May 1
TI  - Green hairy basil seed mucilage biosorbent for dispersive solid phase extraction 
      enrichment of tetracyclines in bovine milk samples followed by HPLC analysis.
PG  - 125645
LID - S0039-9140(24)00024-9 [pii]
LID - 10.1016/j.talanta.2024.125645 [doi]
AB  - Unmodified hairy basil seed mucilage (Ocimum basilicum L.), with attractive 
      features as structural functionality and adsorption capacity, was employed as a 
      green biosorbent for dispersive solid phase extraction and enrichment of 
      oxytetracycline, tetracycline, and doxycycline before quantitation by HPLC-UV for 
      the first time. Hairy basil crushed seed increased the contacting surface area 
      and was completely dispersed in the sample solution to extract tetracyclines 
      under acidic condition with the assistance of ultrasonic waves. The analytes in 
      the extraction phase were separated on a C(18) column under isocratic condition 
      with a mobile phase consisted of acetonitrile and trifluoroacetic acid. Influence 
      of chemical and physical variables on the extraction efficiency of the developed 
      method was investigated and optimized systematically. Under the optimal condition 
      of all experimental parameters, good linear ranges were obtained at 
      15.0-500 mug L(-1) for tetracyclines with determination coefficients more than 
      0.9994. Limits of detection (LODs) and limits of quantitation (LOQs) ranged 
      5.0-7.0 and 15.0 mug L(-1), respectively. Relative standard deviations (RSDs) of 
      the proposed method at 100 and 300 mug L(-1) for TCs were less than 13 % and 10 %, 
      respectively with percentage TC recoveries from spiked standard ranging 
      83.1-109.9 %. This simple, reliable, cost-effective, and environmentally friendly 
      method was successfully applied for the analysis of tetracycline residues in 
      milk. The greenness of the proposed method was assessed using the Analytical 
      Eco-Scale and AGREE protocol.
CI  - Copyright (c) 2024 Elsevier B.V. All rights reserved.
FAU - Nakhonchai, Nongnapas
AU  - Nakhonchai N
AD  - Department of Chemistry and Center of Excellence for Innovation in Chemistry, 
      Faculty of Science, Mahasarakham University, Maha Sarakham, 44150, Thailand.
FAU - Prompila, Nattaya
AU  - Prompila N
AD  - Department of Chemistry and Center of Excellence for Innovation in Chemistry, 
      Faculty of Science, Mahasarakham University, Maha Sarakham, 44150, Thailand.
FAU - Ponhong, Kraingkrai
AU  - Ponhong K
AD  - Department of Chemistry and Center of Excellence for Innovation in Chemistry, 
      Faculty of Science, Mahasarakham University, Maha Sarakham, 44150, Thailand; 
      Multidisciplinary Research Unit of Pure and Applied Chemistry, Department of 
      Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of 
      Science, Mahasarakham University, Maha Sarakham, 44150, Thailand.
FAU - Siriangkhawut, Watsaka
AU  - Siriangkhawut W
AD  - Department of Chemistry and Center of Excellence for Innovation in Chemistry, 
      Faculty of Science, Mahasarakham University, Maha Sarakham, 44150, Thailand.
FAU - Vichapong, Jitlada
AU  - Vichapong J
AD  - Department of Chemistry and Center of Excellence for Innovation in Chemistry, 
      Faculty of Science, Mahasarakham University, Maha Sarakham, 44150, Thailand; 
      Multidisciplinary Research Unit of Pure and Applied Chemistry, Department of 
      Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of 
      Science, Mahasarakham University, Maha Sarakham, 44150, Thailand.
FAU - Supharoek, Sam-Ang
AU  - Supharoek SA
AD  - Department of Medical Science, Amnatcharoen Campus, Mahidol University, Amnat 
      Charoen, 3700, Thailand; Department of Chemistry and Center for Innovation in 
      Chemistry, Faculty of Science, Mahidol University, Bangkok, 10400, Thailand. 
      Electronic address: samang.sup@mahidol.ac.th.
LA  - eng
PT  - Journal Article
DEP - 20240108
PL  - Netherlands
TA  - Talanta
JT  - Talanta
JID - 2984816R
RN  - 0 (Tetracyclines)
RN  - F8VB5M810T (Tetracycline)
RN  - 0 (Anti-Bacterial Agents)
SB  - IM
MH  - Animals
MH  - *Tetracyclines/analysis
MH  - Chromatography, High Pressure Liquid/methods
MH  - *Ocimum basilicum
MH  - Tetracycline/analysis
MH  - Milk/chemistry
MH  - Anti-Bacterial Agents/analysis
MH  - Solid Phase Extraction/methods
OTO - NOTNLM
OT  - Antibiotic
OT  - Extraction method
OT  - Food sample
OT  - Natural adsorbent
OT  - Sample preconcentration
COIS- Declaration of competing interest The authors declare that they have no known 
      competing financial interests or personal relationships that could have appeared 
      to influence the work reported in this paper.
EDAT- 2024/01/15 00:42
MHDA- 2024/02/26 06:42
CRDT- 2024/01/14 18:05
PHST- 2023/09/27 00:00 [received]
PHST- 2024/01/02 00:00 [revised]
PHST- 2024/01/06 00:00 [accepted]
PHST- 2024/02/26 06:42 [medline]
PHST- 2024/01/15 00:42 [pubmed]
PHST- 2024/01/14 18:05 [entrez]
AID - S0039-9140(24)00024-9 [pii]
AID - 10.1016/j.talanta.2024.125645 [doi]
PST - ppublish
SO  - Talanta. 2024 May 1;271:125645. doi: 10.1016/j.talanta.2024.125645. Epub 2024 Jan 
      8.