PMID- 38251097
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20240129
IS  - 2079-4991 (Print)
IS  - 2079-4991 (Electronic)
IS  - 2079-4991 (Linking)
VI  - 14
IP  - 2
DP  - 2024 Jan 5
TI  - Coordination-Polymer-Derived Cu-CoO/C Nanocomposite Used in Fenton-like Reaction 
      to Achieve Efficient Degradation of Organic Compounds.
LID - 10.3390/nano14020132 [doi]
LID - 132
AB  - In this paper, carbon-matrix-supported copper (Cu) and cobaltous oxide (CoO) 
      nanoparticles were obtained by using coordination polymers (CPs) as a precursor. 
      The aqueous solutions of copper methacrylate (CuMA) and cobalt methacrylate 
      (CoMA) were preferentially prepared, which were then mixed with anhydrous ethanol 
      to fabricate dual metal ion coordination polymers (CuMA/CoMA). After calcination 
      under an argon atmosphere, the Cu-CoO/C nanocomposite was obtained. Scanning 
      electron microscope (SEM) and transmission electron microscope (TEM) showed that 
      the material has banded morphology, and the dual functional nanoparticles were 
      highly dispersed in the carbon matrix. The prepared material was used in a 
      heterogeneous Fenton-like reaction, with the aim of replacing traditional ferric 
      catalysts to solve pH constraints and the mass production of ferric slime. The 
      obtained nanocomposite showed excellent catalytic performance on the degradation 
      of methylene blue (MB) at near-neutral conditions; the discoloration efficiency 
      is about 98.5% within 50 min in the presence of 0.15 mmol/mL H(2)O(2) and 0.5 
      mg/mL catalyst. And good reusability was verified via eight cycles. The plausible 
      pathway for MB discoloration and the possible catalytic mechanism was also 
      proposed.
FAU - Xu, Linxu
AU  - Xu L
AUID- ORCID: 0000-0002-7994-6952
AD  - Institute of Resources and Environment Innovation, Shandong Jianzhu University, 
      Jinan 250101, China.
FAU - Liu, Rupeng
AU  - Liu R
AD  - Institute of Resources and Environment Innovation, Shandong Jianzhu University, 
      Jinan 250101, China.
FAU - Zhao, Yubo
AU  - Zhao Y
AD  - Institute of Resources and Environment Innovation, Shandong Jianzhu University, 
      Jinan 250101, China.
FAU - Shen, Xue
AU  - Shen X
AD  - Institute of Resources and Environment Innovation, Shandong Jianzhu University, 
      Jinan 250101, China.
FAU - Sun, Cuizhen
AU  - Sun C
AD  - School of Municipal and Environmental Engineering, Shandong Jianzhu University, 
      Jinan 250101, China.
FAU - Yang, Zhigang
AU  - Yang Z
AD  - Institute of Resources and Environment Innovation, Shandong Jianzhu University, 
      Jinan 250101, China.
FAU - Wang, Jin
AU  - Wang J
AD  - Institute of Resources and Environment Innovation, Shandong Jianzhu University, 
      Jinan 250101, China.
FAU - Du, Yufeng
AU  - Du Y
AD  - Institute of Resources and Environment Innovation, Shandong Jianzhu University, 
      Jinan 250101, China.
FAU - Geng, Shuying
AU  - Geng S
AD  - Institute of Resources and Environment Innovation, Shandong Jianzhu University, 
      Jinan 250101, China.
FAU - Chen, Feiyong
AU  - Chen F
AD  - Institute of Resources and Environment Innovation, Shandong Jianzhu University, 
      Jinan 250101, China.
AD  - Jianda Ecological Environment Innovation Center, Shandong Jianzhu University, 
      Huzhou 313000, China.
LA  - eng
GR  - No. 0031502/the financial support from Shandong Top Talent Special Fundation/
GR  - No. X21074Z/the Doctoral Research Foundation of Shandong Jianzhu University/
PT  - Journal Article
DEP - 20240105
PL  - Switzerland
TA  - Nanomaterials (Basel)
JT  - Nanomaterials (Basel, Switzerland)
JID - 101610216
PMC - PMC10819537
OTO - NOTNLM
OT  - Fenton-like reaction
OT  - carbon
OT  - catalyst
OT  - cobaltous oxide
OT  - copper
COIS- The authors declare no conflicts of interest.
EDAT- 2024/01/22 06:42
MHDA- 2024/01/22 06:43
PMCR- 2024/01/05
CRDT- 2024/01/22 05:39
PHST- 2023/11/10 00:00 [received]
PHST- 2023/12/28 00:00 [revised]
PHST- 2024/01/03 00:00 [accepted]
PHST- 2024/01/22 06:43 [medline]
PHST- 2024/01/22 06:42 [pubmed]
PHST- 2024/01/22 05:39 [entrez]
PHST- 2024/01/05 00:00 [pmc-release]
AID - nano14020132 [pii]
AID - nanomaterials-14-00132 [pii]
AID - 10.3390/nano14020132 [doi]
PST - epublish
SO  - Nanomaterials (Basel). 2024 Jan 5;14(2):132. doi: 10.3390/nano14020132.