PMID- 38287657
OWN - NLM
STAT- MEDLINE
DCOM- 20240220
LR  - 20240220
IS  - 1532-4109 (Electronic)
IS  - 0360-1234 (Linking)
VI  - 59
IP  - 3
DP  - 2024
TI  - Dissipation behaviors of deltamethrin, emamectin benzoate and hexythiazox in 
      grape under field conditions.
PG  - 123-129
LID - 10.1080/03601234.2024.2308487 [doi]
AB  - The objective of this study was to evaluate the dissipation kinetics of 
      deltamethrin, emamectin benzoate, and hexythiazox in grapes. The QuEChERS method 
      was employed and validated for the precise determination of these three 
      pesticides using liquid chromatography-tandem mass spectrometry (LC-MS/MS). 
      Excellent linearity was observed with regression coefficients exceeding 0.998. 
      Notably, the limits of quantification (LOQ) were significantly lower than the 
      maximum residue limits (MRLs) established for grapes by the European Union. The 
      QuEChERS method l recovered 93.23% of the pesticides with an acceptable RSD of 
      5.35% (n = 180), demonstrating its suitability for quantifying them in grapes. 
      Half-lives of deltamethrin, emamectin benzoate, and hexythiazox in grapes were 
      2.62-2.68 days, 8.15-7.30 days, and 3.24-4.01 days, respectively, for both single 
      and double doses. Residues of all pesticides fell below the MRLs by the 
      preharvest interval. This suggests that their application can be considered safe 
      for grapes, ensuring both pest control and consumer safety.
FAU - Balkan, Tarik
AU  - Balkan T
AUID- ORCID: 0000-0003-4756-4842
AD  - Department of Plant Protection, Faculty of Agriculture, Tokat Gaziosmanpasa 
      University, Tokat, Turkiye.
FAU - Yagci, Adem
AU  - Yagci A
AUID- ORCID: 0000-0002-3650-4679
AD  - Department of Horticulture, Faculty of Agriculture, Tokat Gaziosmanpasa 
      University, Tokat, Turkiye.
FAU - Kara, Kenan
AU  - Kara K
AUID- ORCID: 0000-0003-0439-5639
AD  - Department of Plant Protection, Faculty of Agriculture, Tokat Gaziosmanpasa 
      University, Tokat, Turkiye.
LA  - eng
PT  - Journal Article
DEP - 20240129
PL  - England
TA  - J Environ Sci Health B
JT  - Journal of environmental science and health. Part. B, Pesticides, food 
      contaminants, and agricultural wastes
JID - 7607167
RN  - HVM3G4A01W (emamectin benzoate)
RN  - 0 (5-(4-chlorophenyl)-N-cyclohexyl-4-methyl-2-oxothiazolidine-3 carboxamide)
RN  - 2JTS8R821G (decamethrin)
RN  - 0 (Pesticides)
RN  - 0 (Pesticide Residues)
RN  - 70288-86-7 (Ivermectin)
RN  - 0 (Nitriles)
RN  - 0 (Pyrethrins)
RN  - 0 (Thiazolidines)
SB  - IM
MH  - Chromatography, Liquid/methods
MH  - *Vitis
MH  - Tandem Mass Spectrometry/methods
MH  - *Pesticides/analysis
MH  - *Pesticide Residues/analysis
MH  - Ivermectin/*analogs & derivatives
MH  - *Nitriles
MH  - *Pyrethrins
MH  - *Thiazolidines
OTO - NOTNLM
OT  - Degradation rate
OT  - LC-MS/MS
OT  - grape cultivation
OT  - method validation
OT  - pesticide residue
EDAT- 2024/01/30 06:42
MHDA- 2024/02/20 11:51
CRDT- 2024/01/30 01:22
PHST- 2024/02/20 11:51 [medline]
PHST- 2024/01/30 06:42 [pubmed]
PHST- 2024/01/30 01:22 [entrez]
AID - 10.1080/03601234.2024.2308487 [doi]
PST - ppublish
SO  - J Environ Sci Health B. 2024;59(3):123-129. doi: 10.1080/03601234.2024.2308487. 
      Epub 2024 Jan 29.