PMID- 38330462
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20240223
IS  - 1361-6528 (Electronic)
IS  - 0957-4484 (Linking)
VI  - 35
IP  - 19
DP  - 2024 Feb 23
TI  - Porous rod-shaped Fe(2)O(3)/Ag/BP: a novel substrate for highly sensitive SERS 
      detection of persistent organic pollutants.
LID - 10.1088/1361-6528/ad27ab [doi]
AB  - A surface enhanced Raman scattering (SERS) substrate of porous rod-shaped ferric 
      oxide (Fe(2)O(3)) combined with silver nanoparticles (Ag NPs) and black 
      phosphorus (Fe(2)O(3)/Ag/BP) was fabricated to detect the persistent organic 
      pollutants (POPs) at low concentration. The organic pollutant Rhodamine 6G (R6G) 
      was used as the probe molecule to study the performances of Fe(2)O(3)/Ag/BP, and 
      4-chlorobiphenyl (PCB-3) was the target of detection. The limit of detection 
      (LOD) of R6G based on this novel SERS substrate Fe(2)O(3)/Ag/BP was as low as 1.0 
      x 10(-15)M, which was five orders of magnitude lower than that of Fe(2)O(3)/Ag 
      (10(-10)M). The enhancement factor (EF) of Fe(2)O(3)/Ag/BP was 6.44 x 10(8), 
      which was 3.1 times higher than that of porous rod-shaped Fe(2)O(3)/Ag (2.08 x 
      10(8)). The Raman signal of R6G based on Fe(2)O(3)/Ag/BP had a good homogeneity, 
      and the relative standard deviation (RSD) of Raman signal intensities of R6G at 
      1643 cm(-1)was only 5.97%. Furthermore, the Fe(2)O(3)/Ag/BP substrate exhibited a 
      recyclability through the photocatalytic degradation of R6G. The LOD of PCB-3 
      based on Fe(2)O(3)/Ag/BP was 10(-9)M. Besides, Fe(2)O(3)/Ag/BP had a high SERS 
      activity even it was kept in a centrifuge tube without requiring complicated 
      treatment. These results highlight the potential application of Fe(2)O(3)/Ag/BP 
      for ultra-trace detection of POPs in the environment.
CI  - (c) 2024 IOP Publishing Ltd.
FAU - Chen, Hang
AU  - Chen H
AD  - School of Physics and Electronic Engineering, Jiangsu Key Laboratory of Advanced 
      Laser Materials and Devices, Jiangsu Normal University, Xuzhou, Jiangsu 221116, 
      People's Republic of China.
AD  - Jiangsu Xiyi Advanced Materials Research Institute of Industrial Technology, 
      Xuzhou 221400, People's Republic of China.
FAU - Han, Caiqin
AU  - Han C
AUID- ORCID: 0000-0002-0570-1426
AD  - School of Physics and Electronic Engineering, Jiangsu Key Laboratory of Advanced 
      Laser Materials and Devices, Jiangsu Normal University, Xuzhou, Jiangsu 221116, 
      People's Republic of China.
FAU - Zhang, Le
AU  - Zhang L
AD  - School of Physics and Electronic Engineering, Jiangsu Key Laboratory of Advanced 
      Laser Materials and Devices, Jiangsu Normal University, Xuzhou, Jiangsu 221116, 
      People's Republic of China.
AD  - Jiangsu Xiyi Advanced Materials Research Institute of Industrial Technology, 
      Xuzhou 221400, People's Republic of China.
FAU - Wu, Ying
AU  - Wu Y
AUID- ORCID: 0000-0002-8037-2482
AD  - School of Physics and Electronic Engineering, Jiangsu Key Laboratory of Advanced 
      Laser Materials and Devices, Jiangsu Normal University, Xuzhou, Jiangsu 221116, 
      People's Republic of China.
LA  - eng
PT  - Journal Article
DEP - 20240223
PL  - England
TA  - Nanotechnology
JT  - Nanotechnology
JID - 101241272
SB  - IM
OTO - NOTNLM
OT  - black phosphorus
OT  - ferric oxide
OT  - persistent organic pollutants
OT  - silver nanoparticles
OT  - surface enhanced raman scattering
EDAT- 2024/02/08 18:42
MHDA- 2024/02/08 18:43
CRDT- 2024/02/08 17:33
PHST- 2023/08/29 00:00 [received]
PHST- 2024/02/08 00:00 [accepted]
PHST- 2024/02/08 18:43 [medline]
PHST- 2024/02/08 18:42 [pubmed]
PHST- 2024/02/08 17:33 [entrez]
AID - 10.1088/1361-6528/ad27ab [doi]
PST - epublish
SO  - Nanotechnology. 2024 Feb 23;35(19). doi: 10.1088/1361-6528/ad27ab.