PMID- 38330759 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20240228 IS - 1873-3557 (Electronic) IS - 1386-1425 (Linking) VI - 311 DP - 2024 Apr 15 TI - A "turn-on" fluorescent sensor based on three-component covalent organic framework for trace water detection. PG - 123978 LID - S1386-1425(24)00144-6 [pii] LID - 10.1016/j.saa.2024.123978 [doi] AB - Trace amount of H(2)O is difficult to eliminate in laboratory environments and chemical industries as impurities. In some chemical reactions, trace amount of H(2)O can alter final reaction products, yield, and selectivity. So, the detection of trace H(2)O is very important. Herein, a series of TFPT([X])-BMTH- covalent organic frameworks (COFs) (X = 0, 33, 50, 67, 100 %) with intramolecular charge transfer effect (ICT) and aggregate-induced emission (AIE) characteristics were synthesized by amino-aldehyde condensation reaction between 2,5-bis(2-methoxyethoxy)terephthalohydrazide (BMTH)/ 1,3,5-tris(p-formylphenyl)benzene (TFPB) and 4,4',4''-(1,3,5-triazine-2,4,6-triyl)tribenzaldehyde (TFPT). By changing TFPT' content in TFPT([X])-BMTH-COFs, the ICT and AIE of TFPT([X])-BMTH-COFs can be controlled, and accordingly the response to trace H(2)O can be adjusted. A H(2)O sensor based on TFPT([67])-BMTH-COF with a wide linear range from 0 wt% to 0.5 wt% was developed and the detection limit was 0.00007 wt%. In addition, a portable fluorescent test paper based on TFPT([67])-BMTH-COF for visual detection of trace H(2)O in honey samples and salt was constructed. This work has important guiding significance for the development of fluorescent probes for the visual detection of trace water. CI - Copyright (c) 2024 Elsevier B.V. All rights reserved. FAU - Zou, Liangmei AU - Zou L AD - Key Lab of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education, College of Chemistry and Chemical Engineering, Jiangxi Normal University, 99 Ziyang Road, Nanchang 330022, China. FAU - Li, Mengyao AU - Li M AD - Key Lab of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education, College of Chemistry and Chemical Engineering, Jiangxi Normal University, 99 Ziyang Road, Nanchang 330022, China. FAU - Wang, Xinyi AU - Wang X AD - Key Lab of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education, College of Chemistry and Chemical Engineering, Jiangxi Normal University, 99 Ziyang Road, Nanchang 330022, China. FAU - Ye, Meiling AU - Ye M AD - Key Lab of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education, College of Chemistry and Chemical Engineering, Jiangxi Normal University, 99 Ziyang Road, Nanchang 330022, China. FAU - Chen, Lili AU - Chen L AD - Key Lab of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education, College of Chemistry and Chemical Engineering, Jiangxi Normal University, 99 Ziyang Road, Nanchang 330022, China. FAU - Wang, Li AU - Wang L AD - Key Lab of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education, College of Chemistry and Chemical Engineering, Jiangxi Normal University, 99 Ziyang Road, Nanchang 330022, China. FAU - Song, Yonghai AU - Song Y AD - Key Lab of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education, College of Chemistry and Chemical Engineering, Jiangxi Normal University, 99 Ziyang Road, Nanchang 330022, China. Electronic address: yhsong@jxnu.edu.cn. LA - eng PT - Journal Article DEP - 20240201 PL - England TA - Spectrochim Acta A Mol Biomol Spectrosc JT - Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy JID - 9602533 SB - IM OTO - NOTNLM OT - Aggregation induced emission OT - Covalent organic framework OT - Fluorescence sensor OT - Intramolecular charge transfer OT - Trace water COIS- Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. EDAT- 2024/02/09 00:42 MHDA- 2024/02/09 00:43 CRDT- 2024/02/08 18:10 PHST- 2023/11/18 00:00 [received] PHST- 2024/01/10 00:00 [revised] PHST- 2024/01/28 00:00 [accepted] PHST- 2024/02/09 00:43 [medline] PHST- 2024/02/09 00:42 [pubmed] PHST- 2024/02/08 18:10 [entrez] AID - S1386-1425(24)00144-6 [pii] AID - 10.1016/j.saa.2024.123978 [doi] PST - ppublish SO - Spectrochim Acta A Mol Biomol Spectrosc. 2024 Apr 15;311:123978. doi: 10.1016/j.saa.2024.123978. Epub 2024 Feb 1.