PMID- 38336365
OWN - NLM
STAT- Publisher
LR  - 20240220
IS  - 1521-4095 (Electronic)
IS  - 0935-9648 (Linking)
DP  - 2024 Feb 9
TI  - Anion-Reinforced Solvating Ionic Liquid Electrolytes Enabling Stable High-Nickel 
      Cathode in Lithium-Metal Batteries.
PG  - e2400537
LID - 10.1002/adma.202400537 [doi]
AB  - Ionic liquid electrolytes (ILEs) are promising to develop high-safety and 
      high-energy-density lithium-metal batteries (LMBs). Unfortunately, ILEs normally 
      face the challenge of sluggish Li(+) transport due to increased ions' clustering 
      caused by Coulombic interactions. Here a type of anion-reinforced solvating ILEs 
      (ASILEs) is discovered, which reduce ions' clustering by enhancing the 
      anion-cation coordination and promoting more anions to enter the internal 
      solvation sheath of Li(+) to address this concern. The designed ASILEs, 
      incorporating chlorinated hydrocarbons and two anions, bis(fluorosulfonyl) imide 
      (FSI(-) ) and bis(trifluoromethanesulfonyl) imide (TFSI(-) ), aim to enhance 
      Li(+) transport ability, stabilize the interface of the high-nickel cathode 
      material (LiNi(0.8) Co(0.1) Mn(0.1) O(2) , NCM811), and retain fire-retardant 
      properties. With these ASILEs, the Li/NCM811 cell exhibits high initial specific 
      capacity (203 mAh g(-1) at 0.1 C), outstanding capacity retention (81.6% over 500 
      cycles at 1.0 C), and excellent average Coulombic efficiency (99.9% over 500 
      cycles at 1.0 C). Furthermore, an Ah-level Li/NCM811 pouch cell achieves a 
      notable energy density of 386 Wh kg(-1) , indicating the practical feasibility of 
      this electrolyte. This research offers a practical solution and fundamental 
      guidance for the rational design of advanced ILEs, enabling the development of 
      high-safety and high-energy-density LMBs.
CI  - (c) 2024 Wiley-VCH GmbH.
FAU - Zou, Wenhong
AU  - Zou W
AD  - College of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China.
FAU - Zhang, Jun
AU  - Zhang J
AD  - College of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China.
FAU - Liu, Mengying
AU  - Liu M
AD  - College of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China.
FAU - Li, Jidao
AU  - Li J
AD  - College of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China.
FAU - Ren, Zejia
AU  - Ren Z
AD  - College of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China.
FAU - Zhao, Wenlong
AU  - Zhao W
AD  - College of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China.
AD  - CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano-Tech and 
      Nano-Bionics Chinese Academy of Science, Suzhou, 215123, China.
FAU - Zhang, Yanyan
AU  - Zhang Y
AD  - College of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China.
FAU - Shen, Yanbin
AU  - Shen Y
AD  - CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano-Tech and 
      Nano-Bionics Chinese Academy of Science, Suzhou, 215123, China.
FAU - Tang, Yuxin
AU  - Tang Y
AUID- ORCID: 0000-0001-9348-323X
AD  - College of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China.
AD  - Qingyuan Innovation Laboratory, Quanzhou, 362801, China.
LA  - eng
GR  - 2022YFE0206400/National Key Research and Development Program of China/
GR  - 22279017/National Natural Science Foundation of China/
GR  - 00623001/Platform Supporting Fund of Qingyuan Innovation Laboratory/
GR  - 00223002/Key Program of Qingyuan Innovation Laboratory/
PT  - Journal Article
DEP - 20240209
PL  - Germany
TA  - Adv Mater
JT  - Advanced materials (Deerfield Beach, Fla.)
JID - 9885358
SB  - IM
OTO - NOTNLM
OT  - anion reinforced
OT  - high energy density
OT  - ionic liquids
OT  - lithium-metal batteries
EDAT- 2024/02/10 13:18
MHDA- 2024/02/10 13:18
CRDT- 2024/02/09 20:33
PHST- 2024/02/05 00:00 [revised]
PHST- 2024/01/11 00:00 [received]
PHST- 2024/02/10 13:18 [pubmed]
PHST- 2024/02/10 13:18 [medline]
PHST- 2024/02/09 20:33 [entrez]
AID - 10.1002/adma.202400537 [doi]
PST - aheadofprint
SO  - Adv Mater. 2024 Feb 9:e2400537. doi: 10.1002/adma.202400537.