PMID- 38338548
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20240212
IS  - 2304-8158 (Print)
IS  - 2304-8158 (Electronic)
IS  - 2304-8158 (Linking)
VI  - 13
IP  - 3
DP  - 2024 Jan 27
TI  - Assessing Matrix Solid-Phase Dispersion Extraction Strategies for Determining 
      Bisphenols and Phthalates in Gilthead Sea Bream Samples.
LID - 10.3390/foods13030413 [doi]
LID - 413
AB  - Microplastics (MPs) and nanoplastics (NPs) are widely spread in the environment, 
      generating significant concern due to their potential impact on environmental 
      health. Marine species usually ingest plastic fragments, mistaking them for food. 
      Many toxic compounds, such as plastic additives that are not chemically bound to 
      the plastic matrix, can be released from MPs and NPs and reach humans via the 
      food chain. This paper highlights the development and validation of a 
      straightforward solid-liquid extraction clean-up procedure in combination with a 
      matrix solid-phase dispersion method using high-performance liquid chromatography 
      coupled with mass spectrometry (HPLC-MS) detection, enabling facile, precise, and 
      reliable identification and quantitation of a total of six bisphenols and 
      phthalates in gilthead sea breams. Under the optimized conditions, the developed 
      method showed good linearity (R(2) > 0.993) for all target compounds. The 
      recoveries obtained were between 70 and 92%. The relative standard deviations 
      (RSDs) for reproducibility (inter-day) and repeatability (intra-day) were less 
      than 9% and 10%, respectively. The limit of detection (LOD) and limit of 
      quantification (LOQ) for the target compounds ranged from 0.11 to 0.68 microg/kg and 
      from 0.37 to 2.28 microg/kg, respectively. A new, efficient extraction methodology 
      for the determination of BPA, BPS, BPF, DBP, DEP, and DHEP in gilthead seabream 
      has been optimized and validated.
FAU - Soliz, Dulce L
AU  - Soliz DL
AD  - Department of Analytical Science, Faculty of Science, National University of 
      Distance Education, UNED, Las Rozas, 28232 Madrid, Spain.
FAU - Garcinuno, Rosa Ma
AU  - Garcinuno RM
AD  - Department of Analytical Science, Faculty of Science, National University of 
      Distance Education, UNED, Las Rozas, 28232 Madrid, Spain.
FAU - Paniagua Gonzalez, Gema
AU  - Paniagua Gonzalez G
AD  - Department of Analytical Science, Faculty of Science, National University of 
      Distance Education, UNED, Las Rozas, 28232 Madrid, Spain.
FAU - Bravo, Juan Carlos
AU  - Bravo JC
AUID- ORCID: 0000-0002-9961-4314
AD  - Department of Analytical Science, Faculty of Science, National University of 
      Distance Education, UNED, Las Rozas, 28232 Madrid, Spain.
FAU - Fernandez Hernando, Pilar
AU  - Fernandez Hernando P
AD  - Department of Analytical Science, Faculty of Science, National University of 
      Distance Education, UNED, Las Rozas, 28232 Madrid, Spain.
LA  - eng
PT  - Journal Article
DEP - 20240127
PL  - Switzerland
TA  - Foods
JT  - Foods (Basel, Switzerland)
JID - 101670569
PMC - PMC10855760
OTO - NOTNLM
OT  - HPLC-MS
OT  - MSPD
OT  - bisphenols
OT  - gilthead seabream
OT  - phthalates
OT  - plastic contaminants
COIS- The authors declare no conflicts of interest.
EDAT- 2024/02/10 10:46
MHDA- 2024/02/10 10:47
PMCR- 2024/01/27
CRDT- 2024/02/10 01:09
PHST- 2023/12/11 00:00 [received]
PHST- 2024/01/22 00:00 [revised]
PHST- 2024/01/23 00:00 [accepted]
PHST- 2024/02/10 10:47 [medline]
PHST- 2024/02/10 10:46 [pubmed]
PHST- 2024/02/10 01:09 [entrez]
PHST- 2024/01/27 00:00 [pmc-release]
AID - foods13030413 [pii]
AID - foods-13-00413 [pii]
AID - 10.3390/foods13030413 [doi]
PST - epublish
SO  - Foods. 2024 Jan 27;13(3):413. doi: 10.3390/foods13030413.