PMID- 38364498
OWN - NLM
STAT- MEDLINE
DCOM- 20240401
LR  - 20240401
IS  - 1873-7072 (Electronic)
IS  - 0308-8146 (Linking)
VI  - 445
DP  - 2024 Jul 1
TI  - Method development of multi pesticide residue analysis in country beans collected 
      from Dhaka, Bangladesh, and their dietary risk assessment.
PG  - 138741
LID - S0308-8146(24)00390-X [pii]
LID - 10.1016/j.foodchem.2024.138741 [doi]
AB  - The aim of the study was to develop a modified QuEChERS method coupled with 
      liquid chromatography-tandem mass spectrometry (LC-MS/MS) for the simultaneous 
      determination of five multi-class pesticides in country beans collected from 
      Dhaka, Bangladesh. Pesticides were extracted using ACN, and to minimize the 
      co-extraction matrix, optimized d-SPE cleanup was done using sorbents (GCB, PSA, 
      and C18). In the calibration range, the method showed excellent linearity with a 
      correlation coefficient of R(2) >/= 0.9990 both in solvent- and matrix-matched 
      calibration. For the selected pesticides, average recoveries (at four spiking 
      levels (n = 5) of 10, 20, 100, and 200 microg/kg) of 70-100 % were achieved with 
      relative standard deviations (RSDs) </= 9.5 %. The limit of detection (LOD) and 
      limit of quantification (LOQ) ranged from 0.3333 to 1.3333 mug/kg and 1.0 to 
      4.0 mug/kg, respectively. The dietary risk assessment, in terms of hazard quotient 
      (HQ), was calculated to assess consumers' health risks.
CI  - Copyright (c) 2024 Elsevier Ltd. All rights reserved.
FAU - Bhuiya, Ananya
AU  - Bhuiya A
AD  - Institute of National Analytical Research and Service (INARS), Bangladesh Council 
      of Scientific and Industrial Research (BCSIR), Dr. Kudrat-i-Khuda Road, 
      Dhanmondi, Dhaka 1205, Bangladesh; Department of Oceanography, Noakhali Science 
      and Technology University, Noakhali 3814, Bangladesh.
FAU - Yasmin, Sabina
AU  - Yasmin S
AD  - Institute of National Analytical Research and Service (INARS), Bangladesh Council 
      of Scientific and Industrial Research (BCSIR), Dr. Kudrat-i-Khuda Road, 
      Dhanmondi, Dhaka 1205, Bangladesh. Electronic address: sabinayasmin@bcsir.gov.bd.
FAU - Shaikh, Md Aftab Ali
AU  - Shaikh MAA
AD  - Institute of National Analytical Research and Service (INARS), Bangladesh Council 
      of Scientific and Industrial Research (BCSIR), Dr. Kudrat-i-Khuda Road, 
      Dhanmondi, Dhaka 1205, Bangladesh; Department of Chemistry, University of Dhaka, 
      Dhaka 1000, Bangladesh.
FAU - Mustafa, M Golam
AU  - Mustafa MG
AD  - Department of Oceanography, Noakhali Science and Technology University, Noakhali 
      3814, Bangladesh.
FAU - Kabir, Md Humayun
AU  - Kabir MH
AD  - Institute of National Analytical Research and Service (INARS), Bangladesh Council 
      of Scientific and Industrial Research (BCSIR), Dr. Kudrat-i-Khuda Road, 
      Dhanmondi, Dhaka 1205, Bangladesh. Electronic address: humayunkabir@bcsir.gov.bd.
LA  - eng
PT  - Journal Article
DEP - 20240213
PL  - England
TA  - Food Chem
JT  - Food chemistry
JID - 7702639
RN  - 0 (Pesticide Residues)
RN  - 0 (Pesticides)
SB  - IM
MH  - *Pesticide Residues/analysis
MH  - Chromatography, Liquid/methods
MH  - Bangladesh
MH  - Tandem Mass Spectrometry/methods
MH  - *Pesticides/analysis
MH  - Solid Phase Extraction/methods
OTO - NOTNLM
OT  - Azoxystrobin
OT  - Buprofezin
OT  - Carbofuran
OT  - Dimethoate
OT  - Health Risk
OT  - LC-MS/MS
OT  - Pesticide residue
OT  - Pymetrozine
COIS- Declaration of competing interest The authors declare that they have no known 
      competing financial interests or personal relationships that could have appeared 
      to influence the work reported in this paper.
EDAT- 2024/02/17 10:43
MHDA- 2024/04/01 06:43
CRDT- 2024/02/16 18:08
PHST- 2023/11/19 00:00 [received]
PHST- 2024/02/04 00:00 [revised]
PHST- 2024/02/10 00:00 [accepted]
PHST- 2024/04/01 06:43 [medline]
PHST- 2024/02/17 10:43 [pubmed]
PHST- 2024/02/16 18:08 [entrez]
AID - S0308-8146(24)00390-X [pii]
AID - 10.1016/j.foodchem.2024.138741 [doi]
PST - ppublish
SO  - Food Chem. 2024 Jul 1;445:138741. doi: 10.1016/j.foodchem.2024.138741. Epub 2024 
      Feb 13.