PMID- 38382473
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20240314
IS  - 1944-8252 (Electronic)
IS  - 1944-8244 (Linking)
VI  - 16
IP  - 10
DP  - 2024 Mar 13
TI  - Dipole Field-Driven Organic-Inorganic Heterojunction for Highly Sensitive 
      Ultraviolet Photodetector.
PG  - 12754-12764
LID - 10.1021/acsami.3c16985 [doi]
AB  - Developing high-performance organic-inorganic ultraviolet (UV) photodetectors 
      (PDs) has attracted considerable attention. However, this development has been 
      hindered due to poor directional charge-transfer ratios in transport layers, 
      excessive costs, and an ambiguous underlying mechanism. To tackle these 
      challenges, we constructed a heterojunction of economic Mg-doped ZnO (MgZnO) 
      nanorods and poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) [PEDOT:PSS 
      (P:P)] that utilizes dipole field-driven spontaneous polarization to enhance 
      photogenerated charge kinetics. As a result, the proposed heterojunction has an 
      improved noise equivalent power of 3.16 x 10(-11) W Hz(-1/2)), a normalized 
      detection rate (D*) of 8.96 x 10(9) jones, and external quantum efficiency 
      comparable to other ZnO-based devices. Notably, the prepared PDs showed a 
      photocurrent of 4.8 x 10(-3) muA under a faint UV light having an intensity of 1 x 
      10(-5) W cm(-2), exceeding the performance of the most state-of-the-art ZnO-based 
      UV sensors. The introduction of Mg into ZnO is responsible for the high 
      performance, as it causes a lattice mismatch and distortion of the Mg-doped ZnO 
      unit cell. It results in improved dipole movement and the creation of a dipole 
      field, accelerating the directional electron-transfer process. Using a dipole 
      field to manipulate the migration and transport of photogenerated carriers 
      represents a promising approach for achieving outstanding performance in UV PDs.
FAU - Li, Minghao
AU  - Li M
AD  - School of Marine Engineering Equipment, Zhejiang Ocean University, Zhoushan, 
      Zhejiang 316022, China.
FAU - Wu, Cheng
AU  - Wu C
AD  - School of Marine Engineering Equipment, Zhejiang Ocean University, Zhoushan, 
      Zhejiang 316022, China.
FAU - Chen, Mengshan
AU  - Chen M
AD  - National Engineering Research Center for Marine Aquaculture, Zhejiang Ocean 
      University, Zhoushan, Zhejiang 316022, China.
FAU - Weng, Tianfeng
AU  - Weng T
AD  - School of Marine Engineering Equipment, Zhejiang Ocean University, Zhoushan, 
      Zhejiang 316022, China.
FAU - Yu, Xuan
AU  - Yu X
AUID- ORCID: 0009-0003-5265-5287
AD  - School of Marine Engineering Equipment, Zhejiang Ocean University, Zhoushan, 
      Zhejiang 316022, China.
AD  - National Engineering Research Center for Marine Aquaculture, Zhejiang Ocean 
      University, Zhoushan, Zhejiang 316022, China.
FAU - Lin, Kun
AU  - Lin K
AD  - School of Marine Engineering Equipment, Zhejiang Ocean University, Zhoushan, 
      Zhejiang 316022, China.
FAU - Cao, Yu
AU  - Cao Y
AUID- ORCID: 0000-0002-0858-0674
AD  - School of Electrical Engineering, Northeast Electric Power University, Jilin 
      132012, China.
FAU - Yu, Xiaoming
AU  - Yu X
AD  - School of Marine Engineering Equipment, Zhejiang Ocean University, Zhoushan, 
      Zhejiang 316022, China.
AD  - National Engineering Research Center for Marine Aquaculture, Zhejiang Ocean 
      University, Zhoushan, Zhejiang 316022, China.
FAU - Li, Zhenhua
AU  - Li Z
AD  - School of Marine Engineering Equipment, Zhejiang Ocean University, Zhoushan, 
      Zhejiang 316022, China.
FAU - Qiao, Qian
AU  - Qiao Q
AD  - School of Marine Engineering Equipment, Zhejiang Ocean University, Zhoushan, 
      Zhejiang 316022, China.
FAU - Zhang, Hai
AU  - Zhang H
AD  - School of Marine Engineering Equipment, Zhejiang Ocean University, Zhoushan, 
      Zhejiang 316022, China.
FAU - Zhou, Yingtang
AU  - Zhou Y
AUID- ORCID: 0000-0002-8678-295X
AD  - National Engineering Research Center for Marine Aquaculture, Zhejiang Ocean 
      University, Zhoushan, Zhejiang 316022, China.
AD  - Zhejiang Key Laboratory of Petrochemical Environmental Pollution Control, Marine 
      Science and Technology College, Zhejiang Ocean University, Zhoushan, Zhejiang 
      316004, China.
LA  - eng
PT  - Journal Article
DEP - 20240221
PL  - United States
TA  - ACS Appl Mater Interfaces
JT  - ACS applied materials & interfaces
JID - 101504991
SB  - IM
OTO - NOTNLM
OT  - MgZnO nanorods
OT  - built-in potential field
OT  - dipole field
OT  - highly sensitive UV photodetector
OT  - organic-inorganic heterojunction
EDAT- 2024/02/22 00:42
MHDA- 2024/02/22 00:43
CRDT- 2024/02/21 18:23
PHST- 2024/02/22 00:43 [medline]
PHST- 2024/02/22 00:42 [pubmed]
PHST- 2024/02/21 18:23 [entrez]
AID - 10.1021/acsami.3c16985 [doi]
PST - ppublish
SO  - ACS Appl Mater Interfaces. 2024 Mar 13;16(10):12754-12764. doi: 
      10.1021/acsami.3c16985. Epub 2024 Feb 21.