PMID- 38427459
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20240314
IS  - 1944-8252 (Electronic)
IS  - 1944-8244 (Linking)
VI  - 16
IP  - 10
DP  - 2024 Mar 13
TI  - Protective and Flame-Retardant Bifunctional Epoxy-Based Nanocomposite Coating by 
      Intercomponent Synergy between Modified CaAl-LDH and rGO.
PG  - 13114-13131
LID - 10.1021/acsami.3c19245 [doi]
AB  - Extensive utilization in various settings poses extra requirements of coatings 
      beyond just anticorrosion properties. Herein, 8-hydroxyquinoline (8-HQ) 
      intercalated CaAl-based layered double hydroxide (CaAl-8HQ-LDH) was loaded on 
      reduced GO (rGO) through a one-pot hydrothermal reaction, which was employed as 
      the nanofiller endowing the epoxy (EP/CaAl-8HQ LDH@rGO) with excellent 
      flame-retardancy while ensuring efficient protection for mild steel. Results of 
      electrochemical impedance spectroscopy (EIS) demonstrated the durability of the 
      EP/CaAl-8HQ LDH@rGO-coated specimen, with the impedance at the lowest frequency 
      (|Z|(0.01Hz)) maintained as 1.84 x 10(10) Omega cm(2) after 120 days of immersion in 
      a 3.5 wt % NaCl solution. Even for the scratched EP/CaAl-8HQ LDH@rGO system, only 
      a slight decline in |Z|(0.01Hz) was observed during 180 h of exposure to the NaCl 
      solution, indicating a self-healing feature supported by salt spray tests. UL-94 
      burning tests revealed the V-0 rating for EP/CaAl-8HQ LDH@rGO with improved 
      thermostability. Strong physical barrier from two-dimensional rGO and the release 
      of 8-HQ from LDH interlayers accounted for the anticorrosive and self-healing 
      properties. However, O(2)-concentration dilution and charring-layer promotion 
      governed the flame-retardant behavior of the nanocomposite coating. The 
      intercomponent synergy of nanofillers achieved in this work may provide a useful 
      reference for designing multifunctional coatings.
FAU - Murtaza, Hassan
AU  - Murtaza H
AD  - College of Materials Science and Engineering, Beijing University of Chemical 
      Technology, Beijing 100029, China.
FAU - Zhao, Jingmao
AU  - Zhao J
AUID- ORCID: 0000-0002-9197-4868
AD  - College of Materials Science and Engineering, Beijing University of Chemical 
      Technology, Beijing 100029, China.
AD  - Beijing Key Laboratory of Electrochemical Process and Technology for Materials, 
      Beijing 100029, China.
FAU - Tabish, Mohammad
AU  - Tabish M
AD  - College of Materials Science and Engineering, Beijing University of Chemical 
      Technology, Beijing 100029, China.
FAU - Wang, Jingbao
AU  - Wang J
AD  - College of Materials Science and Engineering, Beijing University of Chemical 
      Technology, Beijing 100029, China.
FAU - Mubeen, Muhammad
AU  - Mubeen M
AD  - College of Materials Science and Engineering, Beijing University of Chemical 
      Technology, Beijing 100029, China.
FAU - Zhang, Jingfan
AU  - Zhang J
AD  - State Key Laboratory of Organic-Inorganic Composites, Beijing University of 
      Chemical Technology, Beijing 100029, China.
FAU - Zhang, Sheng
AU  - Zhang S
AUID- ORCID: 0000-0001-7131-6246
AD  - State Key Laboratory of Organic-Inorganic Composites, Beijing University of 
      Chemical Technology, Beijing 100029, China.
FAU - Fan, Baomin
AU  - Fan B
AUID- ORCID: 0000-0002-0430-5712
AD  - College of Chemical and Materials Engineering, Beijing Technology and Business 
      University, Beijing 100029, China.
LA  - eng
PT  - Journal Article
DEP - 20240301
PL  - United States
TA  - ACS Appl Mater Interfaces
JT  - ACS applied materials & interfaces
JID - 101504991
SB  - IM
OTO - NOTNLM
OT  - corrosion inhibition
OT  - flame-retardant
OT  - layered double hydroxide
OT  - nanocomposites
OT  - pristine epoxy (EP)
OT  - rGO
EDAT- 2024/03/01 18:43
MHDA- 2024/03/01 18:44
CRDT- 2024/03/01 12:22
PHST- 2024/03/01 18:44 [medline]
PHST- 2024/03/01 18:43 [pubmed]
PHST- 2024/03/01 12:22 [entrez]
AID - 10.1021/acsami.3c19245 [doi]
PST - ppublish
SO  - ACS Appl Mater Interfaces. 2024 Mar 13;16(10):13114-13131. doi: 
      10.1021/acsami.3c19245. Epub 2024 Mar 1.