PMID- 38497589
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20240328
IS  - 1944-8252 (Electronic)
IS  - 1944-8244 (Linking)
VI  - 16
IP  - 12
DP  - 2024 Mar 27
TI  - Aromatic Ethers Induced Electronic Structure Reconstruction on Encapsulated 
      Nickel Catalysts for High-Performance Catalytic Hydrogenation.
PG  - 14680-14693
LID - 10.1021/acsami.3c16381 [doi]
AB  - Carbon-encapsulated metal (CEM) catalysts effectively address supported metal 
      catalyst instability by protecting the active metal with a shell. However, mass 
      transfer limitations lead to reduced activity for catalytic hydrogenation 
      reaction over most CEM catalysts. Herein, we introduce a dopant strategy aimed at 
      incorporating nickel metal within graphene-like shells (GLS) featuring 
      oxygen-containing functional groups (OFGs). The core of this strategy involves 
      precise control of GLS modification and the demonstrated pivotal influence of 
      aromatic ether linkages ( horizontal lineC-O-C) in GLS for significant enhancement of catalytic 
      performance. The introduction of  horizontal lineC-O-C into GLS with stability was beneficial to 
      improve the work function of the catalyst and promoted electron transmission from 
      Ni metal core to GLS, further elevating the catalytic activity, based on the 
      Mott-Schottky effect. In addition, the experimental characterization and density 
      functional theory (DFT) calculations showcased that the  horizontal lineC-O-C reconstructed the 
      electronic state of GLS, imparting it highly specific for the adsorption of 
      hydrogen and para-chloronitrobenzene (p-CNB) to obtain para-chloroaniline (p-CAN) 
      with high selectivity. This work manifested a feasible direction for the precise 
      modulation and design of the OFGs in CEM catalysts to achieve highly efficient 
      catalytic hydrogenation.
FAU - Yao, Yongyue
AU  - Yao Y
AD  - State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, 
      Zhejiang University of Technology, Hangzhou 310032, People's Republic of China.
FAU - Yin, Chunyu
AU  - Yin C
AD  - State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, 
      Zhejiang University of Technology, Hangzhou 310032, People's Republic of China.
FAU - Ma, Chaofan
AU  - Ma C
AD  - State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, 
      Zhejiang University of Technology, Hangzhou 310032, People's Republic of China.
FAU - Li, Yanni
AU  - Li Y
AD  - State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, 
      Zhejiang University of Technology, Hangzhou 310032, People's Republic of China.
FAU - Wang, Yu
AU  - Wang Y
AD  - State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, 
      Zhejiang University of Technology, Hangzhou 310032, People's Republic of China.
FAU - Jiang, Ruikun
AU  - Jiang R
AD  - State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, 
      Zhejiang University of Technology, Hangzhou 310032, People's Republic of China.
FAU - He, Wei
AU  - He W
AD  - State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, 
      Zhejiang University of Technology, Hangzhou 310032, People's Republic of China.
FAU - Xiang, Zhenli
AU  - Xiang Z
AD  - State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, 
      Zhejiang University of Technology, Hangzhou 310032, People's Republic of China.
FAU - Liu, Yi
AU  - Liu Y
AD  - State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, 
      Zhejiang University of Technology, Hangzhou 310032, People's Republic of China.
FAU - Li, Xiaonian
AU  - Li X
AD  - State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, 
      Zhejiang University of Technology, Hangzhou 310032, People's Republic of China.
FAU - Lu, Chunshan
AU  - Lu C
AUID- ORCID: 0000-0002-2485-3070
AD  - State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, 
      Zhejiang University of Technology, Hangzhou 310032, People's Republic of China.
LA  - eng
PT  - Journal Article
DEP - 20240318
PL  - United States
TA  - ACS Appl Mater Interfaces
JT  - ACS applied materials & interfaces
JID - 101504991
SB  - IM
OTO - NOTNLM
OT  - aromatic ether
OT  - catalytic hydrogenation
OT  - graphene-like shells
OT  - oxygen-containing functional groups
OT  - surface modification
EDAT- 2024/03/18 12:44
MHDA- 2024/03/18 12:45
CRDT- 2024/03/18 08:32
PHST- 2024/03/18 12:45 [medline]
PHST- 2024/03/18 12:44 [pubmed]
PHST- 2024/03/18 08:32 [entrez]
AID - 10.1021/acsami.3c16381 [doi]
PST - ppublish
SO  - ACS Appl Mater Interfaces. 2024 Mar 27;16(12):14680-14693. doi: 
      10.1021/acsami.3c16381. Epub 2024 Mar 18.